Sintering of NiO/YSZ Anode Layers for Metal-Supported Solid Oxide Fuel Cell
| Parent link: | Advanced Materials Research: Scientific Journal Vol. 1040 : High Technology: Research and Applications 2014 (HTRA 2014).— 2014.— [P. 155-160] |
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| Corporate Author: | |
| Other Authors: | , , , , , |
| Summary: | Title screen The construction of a metal-supported fuel cell has been recently generating a growing interest among the designers of solid oxide fuel cells. The present work is aimed at solving the problem related to high-temperature sintering of fuel cell NiO/YSZ anode on the porous metal substrate functioning both as a supporting structure and a reliable current collector. Hence, its irreversible oxidation during high-temperature sintering should be avoided. NiO/YSZ layers were applied on porous metal samples by a screen-printing technique and sintered in reducing and inert atmospheres, as well as in vacuum. The obtained layers were studied by means of scanning electron microscopy and X-ray phase analysis. It was shown that a temperature of 1000°С does not ensure a substantial sintering of Ni and YSZ granules in a reducing atmosphere. Under the sintering temperature above 1230°С in an inert atmosphere and vacuum, the nickel oxide dissociation and its massive agglomeration are observed. The conditions of NiO/YSZ layer vacuum sintering were experimentally determined which provide a high-grade sintering of nickel cermet granules without Ni agglomeration, disturbance of homogeneity in the formed anode layer, and the metal substrate oxidation. Режим доступа: по договору с организацией-держателем ресурса |
| Language: | English |
| Published: |
2014
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| Series: | Advanced Materials and Nanotechnology |
| Subjects: | |
| Online Access: | http://dx.doi.org/10.4028/www.scientific.net/AMR.1040.155 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=640906 |
| Summary: | Title screen The construction of a metal-supported fuel cell has been recently generating a growing interest among the designers of solid oxide fuel cells. The present work is aimed at solving the problem related to high-temperature sintering of fuel cell NiO/YSZ anode on the porous metal substrate functioning both as a supporting structure and a reliable current collector. Hence, its irreversible oxidation during high-temperature sintering should be avoided. NiO/YSZ layers were applied on porous metal samples by a screen-printing technique and sintered in reducing and inert atmospheres, as well as in vacuum. The obtained layers were studied by means of scanning electron microscopy and X-ray phase analysis. It was shown that a temperature of 1000°С does not ensure a substantial sintering of Ni and YSZ granules in a reducing atmosphere. Under the sintering temperature above 1230°С in an inert atmosphere and vacuum, the nickel oxide dissociation and its massive agglomeration are observed. The conditions of NiO/YSZ layer vacuum sintering were experimentally determined which provide a high-grade sintering of nickel cermet granules without Ni agglomeration, disturbance of homogeneity in the formed anode layer, and the metal substrate oxidation. Режим доступа: по договору с организацией-держателем ресурса |
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| DOI: | 10.4028/www.scientific.net/AMR.1040.155 |