Sintering of NiO/YSZ Anode Layers for Metal-Supported Solid Oxide Fuel Cell

Bibliographic Details
Parent link:Advanced Materials Research: Scientific Journal
Vol. 1040 : High Technology: Research and Applications 2014 (HTRA 2014).— 2014.— [P. 155-160]
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Физико-технический институт (ФТИ) Кафедра водородной энергетики и плазменных технологий (ВЭПТ)
Other Authors: Soloviev A. A. Andrey Aleksandrovich, Ionov I. V. Igor Vyacheslavovich, Kovalchuk A. N. Anastasia Nikolaevna, Kirdyashkin A. I. Aleksandr Ivanovich, Maznoy A. S. Anatoly Sergeevich, Kitler V. D.
Summary:Title screen
The construction of a metal-supported fuel cell has been recently generating a growing interest among the designers of solid oxide fuel cells. The present work is aimed at solving the problem related to high-temperature sintering of fuel cell NiO/YSZ anode on the porous metal substrate functioning both as a supporting structure and a reliable current collector. Hence, its irreversible oxidation during high-temperature sintering should be avoided. NiO/YSZ layers were applied on porous metal samples by a screen-printing technique and sintered in reducing and inert atmospheres, as well as in vacuum. The obtained layers were studied by means of scanning electron microscopy and X-ray phase analysis. It was shown that a temperature of 1000°С does not ensure a substantial sintering of Ni and YSZ granules in a reducing atmosphere. Under the sintering temperature above 1230°С in an inert atmosphere and vacuum, the nickel oxide dissociation and its massive agglomeration are observed. The conditions of NiO/YSZ layer vacuum sintering were experimentally determined which provide a high-grade sintering of nickel cermet granules without Ni agglomeration, disturbance of homogeneity in the formed anode layer, and the metal substrate oxidation.
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Language:English
Published: 2014
Series:Advanced Materials and Nanotechnology
Subjects:
Online Access:http://dx.doi.org/10.4028/www.scientific.net/AMR.1040.155
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=640906