On the local mode behaviour of the XH2/XD2 and XD/XH fragments with respect to the deuterated species of the near local mode XH3(C3v ) molecule; Molecular Physics; Vol. 107, iss. 14

Bibliografiska uppgifter
Parent link:Molecular Physics: An International Journal at the Interface Between Chemistry and Physics
Vol. 107, iss. 14.— 2009.— [P. 1409-1416]
Huvudupphovsman: Ulenekov (Ulenikov) O. N. Oleg Nikolaevich
Övriga upphovsmän: Bekhtereva E. S. Elena Sergeevna, Leroy K. A. Klod (Claude) Andre
Sammanfattning:Title screen
Effect of isotopic substitution in the near local mode, XH3(C3v ), molecules is considered. On that basis it is shown that the spectroscopic properties of deuterated and/or di-deuterated isotopic species of the XH3(C3v ) molecule with the value of interbond angle close to п/2 are analogous to the spectroscopic properties of its separate fragments: of a three-atomic local mode ‘molecule’ XH2/XD2 and of a diatomic XD/XH ‘molecule’. The phosphine molecule is considered as an illustration.
Режим доступа: по договору с организацией-держателем ресурса
Språk:engelska
Publicerad: 2009
Ämnen:
Länkar:http://dx.doi.org/10.1080/00268970902905828
Materialtyp: Elektronisk Bokavsnitt
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=640784