On the local mode behaviour of the XH2/XD2 and XD/XH fragments with respect to the deuterated species of the near local mode XH3(C3v ) molecule
| Parent link: | Molecular Physics: An International Journal at the Interface Between Chemistry and Physics Vol. 107, iss. 14.— 2009.— [P. 1409-1416] |
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| Main Author: | |
| Other Authors: | , |
| Summary: | Title screen Effect of isotopic substitution in the near local mode, XH3(C3v ), molecules is considered. On that basis it is shown that the spectroscopic properties of deuterated and/or di-deuterated isotopic species of the XH3(C3v ) molecule with the value of interbond angle close to п/2 are analogous to the spectroscopic properties of its separate fragments: of a three-atomic local mode ‘molecule’ XH2/XD2 and of a diatomic XD/XH ‘molecule’. The phosphine molecule is considered as an illustration. Режим доступа: по договору с организацией-держателем ресурса |
| Language: | English |
| Published: |
2009
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| Subjects: | |
| Online Access: | http://dx.doi.org/10.1080/00268970902905828 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=640784 |