High resolution study of the 3v1 band of SO2
| Parent link: | Journal of Molecular Spectroscopy: Scientific Journal Vol. 255, iss. 2.— 2009.— [P. 111–121] |
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| Other Authors: | , , , , |
| Summary: | Title screen The second overtone band 3ν1 of sulfur dioxide has been studied for the first time with high resolution rotation-vibration spectroscopy. About 3000 transitions involving about 900 upper state energy levels with J max = 66 and K max a = 24 have been assigned to the 3ν1 band. In the analysis, an effective Hamiltonian taking into account accidental interactions between the vibrational states (3 0 0), (2 2 0), and (0 4 1) was used. The Watson operator in A-reduction and Ir representation was used in the diagonal blocks of the Hamiltonian. As the result of analysis a set of parameters reproducing the initial experimental data with the rms = 0.00028 cm−1 was obtained. Режим доступа: по договору с организацией-держателем ресурса |
| Published: |
2009
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| Subjects: | |
| Online Access: | http://dx.doi.org/10.1016/j.jms.2009.03.009 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=640782 |