Structure and luminescent properties of the cadmium(II) chloride complex with bis(benzotriazole-1-YL)methane; Journal of Structural Chemistry; Vol. 51, iss. 3
| Parent link: | Journal of Structural Chemistry: Scientific Journal Vol. 51, iss. 3.— 2010.— [P. 514-518] |
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| Awduron Eraill: | , , , , , , , |
| Crynodeb: | Title screen A procedure to synthesize a cadmium(II) chloride complex with bis(benzotriazole-1-yl)methane (L) of the composition [Cd2L(H2O)(C2H5OH)Cl4] n · 1.5nH2O is developed. The compound was studied by single crystal and powder X-ray diffraction. According to the single crystal X-ray data, the complex has a ribbon-polymer structure determined by bidentate bridging type coordination of L to cadmium(II) atoms by N(3) and N(3s’) atoms. Tetramers of cadmium(II) atoms bonded by four bridging fu2- and two fu3-coordinated Cl atoms can be distinguished in the structure. The coordination polyhedron of cadmium(II) atoms is a distorted octahedron. The luminescent properties of L and dehydrated initial complex of the composition [Cd2L(H2O)(C2H5OH)Cl4] n are analyzed. It is shown that L has photoluminescence with?max = 477 nm in the blue spectral region, and the complex has photoluminescence in the yellow-orange range with λmax = 577 nm at 300 K and λexc = 365 nm. Режим доступа: по договору с организацией-держателем ресурса |
| Iaith: | Saesneg |
| Cyhoeddwyd: |
2010
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| Pynciau: | |
| Mynediad Ar-lein: | http://dx.doi.org/10.1007/s10947-010-0074-3 |
| Fformat: | Electronig Pennod Llyfr |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=639669 |
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| 200 | 1 | |a Structure and luminescent properties of the cadmium(II) chloride complex with bis(benzotriazole-1-YL)methane |f E. V. Lider [et al.] | |
| 203 | |a Text |c electronic | ||
| 300 | |a Title screen | ||
| 320 | |a [References: p. 518 (14 tit.)] | ||
| 330 | |a A procedure to synthesize a cadmium(II) chloride complex with bis(benzotriazole-1-yl)methane (L) of the composition [Cd2L(H2O)(C2H5OH)Cl4] n · 1.5nH2O is developed. The compound was studied by single crystal and powder X-ray diffraction. According to the single crystal X-ray data, the complex has a ribbon-polymer structure determined by bidentate bridging type coordination of L to cadmium(II) atoms by N(3) and N(3s’) atoms. Tetramers of cadmium(II) atoms bonded by four bridging fu2- and two fu3-coordinated Cl atoms can be distinguished in the structure. The coordination polyhedron of cadmium(II) atoms is a distorted octahedron. The luminescent properties of L and dehydrated initial complex of the composition [Cd2L(H2O)(C2H5OH)Cl4] n are analyzed. It is shown that L has photoluminescence with?max = 477 nm in the blue spectral region, and the complex has photoluminescence in the yellow-orange range with λmax = 577 nm at 300 K and λexc = 365 nm. | ||
| 333 | |a Режим доступа: по договору с организацией-держателем ресурса | ||
| 461 | |t Journal of Structural Chemistry |o Scientific Journal | ||
| 463 | |t Vol. 51, iss. 3 |v [P. 514-518] |d 2010 | ||
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a cadmium | |
| 610 | 1 | |a bis(benzotriazole-1-yl)methane | |
| 610 | 1 | |a complex | |
| 610 | 1 | |a synthesis | |
| 610 | 1 | |a crystal and molecular structure | |
| 610 | 1 | |a luminescent properties | |
| 701 | 1 | |a Lider |b E. V. | |
| 701 | 1 | |a Piryazev |b D. A. | |
| 701 | 1 | |a Virovets |b A. V. | |
| 701 | 1 | |a Lavrenova |b L. G. | |
| 701 | 1 | |a Smolentsev |b A. I. | |
| 701 | 1 | |a Uskov |b E. M. | |
| 701 | 1 | |a Potapov |b A. S. |c Chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1981- |g Andrey Sergeevich |3 (RuTPU)RU\TPU\pers\33909 |9 17482 | |
| 701 | 1 | |a Khlebnikov |b A. I. |c Chemist |c Professor of Tomsk Polytechnic University |f 1963- |g Andrey Ivanovich |3 (RuTPU)RU\TPU\pers\33927 |9 17500 | |
| 801 | 2 | |a RU |b 63413507 |c 20170321 |g RCR | |
| 856 | 4 | |u http://dx.doi.org/10.1007/s10947-010-0074-3 | |
| 942 | |c CF | ||