Structure and luminescent properties of the cadmium(II) chloride complex with bis(benzotriazole-1-YL)methane
| Parent link: | Journal of Structural Chemistry: Scientific Journal Vol. 51, iss. 3.— 2010.— [P. 514-518] |
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| Kolejni autorzy: | , , , , , , , |
| Streszczenie: | Title screen A procedure to synthesize a cadmium(II) chloride complex with bis(benzotriazole-1-yl)methane (L) of the composition [Cd2L(H2O)(C2H5OH)Cl4] n · 1.5nH2O is developed. The compound was studied by single crystal and powder X-ray diffraction. According to the single crystal X-ray data, the complex has a ribbon-polymer structure determined by bidentate bridging type coordination of L to cadmium(II) atoms by N(3) and N(3s’) atoms. Tetramers of cadmium(II) atoms bonded by four bridging fu2- and two fu3-coordinated Cl atoms can be distinguished in the structure. The coordination polyhedron of cadmium(II) atoms is a distorted octahedron. The luminescent properties of L and dehydrated initial complex of the composition [Cd2L(H2O)(C2H5OH)Cl4] n are analyzed. It is shown that L has photoluminescence with?max = 477 nm in the blue spectral region, and the complex has photoluminescence in the yellow-orange range with λmax = 577 nm at 300 K and λexc = 365 nm. Режим доступа: по договору с организацией-держателем ресурса |
| Wydane: |
2010
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| Hasła przedmiotowe: | |
| Dostęp online: | http://dx.doi.org/10.1007/s10947-010-0074-3 |
| Format: | Elektroniczne Rozdział |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=639669 |