Low Temperature n-alkanes Bromination without Catalysts; Procedia Chemistry; Vol. 11 : 1st International Symposium on Inorganic Fluorides: Chemistry and Technology, ISIF 2014, Tomsk, Russia

Low Temperature n-alkanes Bromination without Catalysts; Procedia Chemistry; Vol. 11 : 1st International Symposium on Inorganic Fluorides: Chemistry and Technology, ISIF 2014, Tomsk, Russia

Dades bibliogràfiques
Parent link:	Procedia Chemistry Vol. 11 : 1st International Symposium on Inorganic Fluorides: Chemistry and Technology, ISIF 2014, Tomsk, Russia.— 2014.— [P. 84-87]
Autor corporatiu:	Национальный исследовательский Томский политехнический университет (ТПУ) Физико-технический институт (ФТИ) Кафедра химической технологии редких, рассеянных и радиоактивных элементов (№ 43) (ХТРЭ), Национальный исследовательский Томский политехнический университет (ТПУ) Институт физики высоких технологий (ИФВТ) Кафедра биотехнологии и органической химии (БИОХ)
Altres autors:	Sobolev V. I. Vasily Igorevich, Radchenko V. B. Vyacheslav Borisovich, Ostvald R. V. Roman Vyacheslavovich, Filimonov V. D. Viktor Dmitrievich, Zherin (Gerin) I. I. Ivan Ignatyevich
Sumari:	Title screen It has been observed that Ba (BrF[4])[2] demonstrated a high reactivity towards normal alkanes from C[6]H[14] to C[16]H[34]. It has been found that the reactions ran with intensive self-heating and release of elemental bromine. The GC-MS analysis showed that the main product of Ba (BrF[4])2 interaction with each alkane was its 3-bromoderivative. The optimal interaction parameters have been found. The heat effects of the reaction have been determined by the isothermal calorimetric method, it has been found that the heat effect of the bromination increased with the increase of the length of carbon chain of alkane. Режим доступа: по договору с организацией-держателем ресурса
Idioma:	anglès
Publicat:	2014
Matèries:	электронный ресурс труды учёных ТПУ synthesis bromine trifluoride fluorohalogenates bromination chromatography calorimetry fluorine синтез бром бромирование хроматография калориметрия фтор
Accés en línia:	http://dx.doi.org/10.1016/j.proche.2014.11.015
Format:	Electrònic Capítol de llibre
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=639603

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