Low Temperature n-alkanes Bromination without Catalysts
| Parent link: | Procedia Chemistry Vol. 11 : 1st International Symposium on Inorganic Fluorides: Chemistry and Technology, ISIF 2014, Tomsk, Russia.— 2014.— [P. 84-87] |
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| Corporate Authors: | , |
| Other Authors: | , , , , |
| Summary: | Title screen It has been observed that Ba (BrF[4])[2] demonstrated a high reactivity towards normal alkanes from C[6]H[14] to C[16]H[34]. It has been found that the reactions ran with intensive self-heating and release of elemental bromine. The GC-MS analysis showed that the main product of Ba (BrF[4])2 interaction with each alkane was its 3-bromoderivative. The optimal interaction parameters have been found. The heat effects of the reaction have been determined by the isothermal calorimetric method, it has been found that the heat effect of the bromination increased with the increase of the length of carbon chain of alkane. Режим доступа: по договору с организацией-держателем ресурса |
| Language: | English |
| Published: |
2014
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| Subjects: | |
| Online Access: | http://dx.doi.org/10.1016/j.proche.2014.11.015 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=639603 |