Low Temperature n-alkanes Bromination without Catalysts; Procedia Chemistry; Vol. 11 : 1st International Symposium on Inorganic Fluorides: Chemistry and Technology, ISIF 2014, Tomsk, Russia

Low Temperature n-alkanes Bromination without Catalysts; Procedia Chemistry; Vol. 11 : 1st International Symposium on Inorganic Fluorides: Chemistry and Technology, ISIF 2014, Tomsk, Russia

Библиографические подробности
Источник:Procedia Chemistry
Vol. 11 : 1st International Symposium on Inorganic Fluorides: Chemistry and Technology, ISIF 2014, Tomsk, Russia.— 2014.— [P. 84-87]
Корпоративные авторы: Национальный исследовательский Томский политехнический университет (ТПУ) Физико-технический институт (ФТИ) Кафедра химической технологии редких, рассеянных и радиоактивных элементов (№ 43) (ХТРЭ), Национальный исследовательский Томский политехнический университет (ТПУ) Институт физики высоких технологий (ИФВТ) Кафедра биотехнологии и органической химии (БИОХ)
Другие авторы: Sobolev V. I. Vasily Igorevich, Radchenko V. B. Vyacheslav Borisovich, Ostvald R. V. Roman Vyacheslavovich, Filimonov V. D. Viktor Dmitrievich, Zherin (Gerin) I. I. Ivan Ignatyevich
Примечания:Title screen
It has been observed that Ba (BrF[4])[2] demonstrated a high reactivity towards normal alkanes from C[6]H[14] to C[16]H[34]. It has been found that the reactions ran with intensive self-heating and release of elemental bromine. The GC-MS analysis showed that the main product of Ba (BrF[4])2 interaction with each alkane was its 3-bromoderivative. The optimal interaction parameters have been found. The heat effects of the reaction have been determined by the isothermal calorimetric method, it has been found that the heat effect of the bromination increased with the increase of the length of carbon chain of alkane.
Режим доступа: по договору с организацией-держателем ресурса
Язык:английский
Опубликовано: 2014
Предметы:
электронный ресурс
труды учёных ТПУ
synthesis
bromine trifluoride
fluorohalogenates
bromination
chromatography
calorimetry
fluorine
синтез
бром
бромирование
хроматография
калориметрия
фтор
Online-ссылка:http://dx.doi.org/10.1016/j.proche.2014.11.015
Формат: Электронный ресурс Статья
Запись в KOHA:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=639603
Описание
Примечания:Title screen
It has been observed that Ba (BrF[4])[2] demonstrated a high reactivity towards normal alkanes from C[6]H[14] to C[16]H[34]. It has been found that the reactions ran with intensive self-heating and release of elemental bromine. The GC-MS analysis showed that the main product of Ba (BrF[4])2 interaction with each alkane was its 3-bromoderivative. The optimal interaction parameters have been found. The heat effects of the reaction have been determined by the isothermal calorimetric method, it has been found that the heat effect of the bromination increased with the increase of the length of carbon chain of alkane.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1016/j.proche.2014.11.015

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