Crystallographic Studies of Cesium Tetrafluorobromates(III)

Bibliographic Details
Parent link:Procedia Chemistry
Vol. 11 : 1st International Symposium on Inorganic Fluorides: Chemistry and Technology, ISIF 2014, Tomsk, Russia.— 2014.— [P. 35-42]
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Физико-технический институт (ФТИ) Кафедра химической технологии редких, рассеянных и радиоактивных элементов (№ 43) (ХТРЭ)
Other Authors: Ivlev S. I. Sergey Ivanovich, Woidy P., Zherin (Gerin) I. I. Ivan Ignatyevich, Ostvald R. V. Roman Vyacheslavovich, Kraus F., Voytenko M. Yu., Shagalov V. V. Vladimir Vladimirovich
Summary:Title screen
This article describes CsBr[2]F[7] (1) which has been obtained in the form of colorless single crystals. Shown by the X-ray diffraction on single crystals its Br[2]F[7]{-} anion is neither planar nor is its Br-µ-F-Br unit linear, as previously deduced from Raman spectra. Also a regular tetrafluorobromate CsBrF[4] (2) has been obtained in the form of a colorless powder. Compound 2 can also be obtained from compound 1 by evacuation. The crystal structure of CsBrF[4] (2) has been elucidated by the Rietveld refinement on its X-ray powder pattern.
Режим доступа: по договору с организацией-держателем ресурса
Published: 2014
Subjects:
Online Access:http://dx.doi.org/10.1016/j.proche.2014.11.008
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=639591