Synthesis, crystal structure and electrocatalytic activity of discrete and polymeric copper(II) complexes with bitopic bis(pyrazol-1-yl)methane ligands; Inorganic Chemistry Communications; Vol. 53

Chi tiết về thư mục
Parent link:Inorganic Chemistry Communications
Vol. 53.— 2015.— [P. 72-75]
Tác giả của công ty: Национальный исследовательский Томский политехнический университет (ТПУ) Институт физики высоких технологий (ИФВТ) Кафедра биотехнологии и органической химии (БИОХ)
Tác giả khác: Potapov A. S. Andrey Sergeevich, Nudnova E. A., Khlebnikov A. I. Andrey Ivanovich, Ogorodnikov V. D., Petrenko T. V.
Tóm tắt:Title screen
New coordination copper(II) compounds containing bitopic bis(pyrazol-1-yl)methane ligands, namely 1,1,2,2-tetrakis(pyrazol-1-yl)ethane, 1,4-bis[bis(pyrazol-1-yl)methyl]benzene and 1,4-bis[bis(3,5-dimethylpyrazol-1-yl)methyl]benzene were prepared. Reactions of ligands with Cu2 + ions in 1:2 ratio gave discrete homodinuclear complexes, while 1:1 ligand-to-metal ratio lead to the formation of coordination polymers. Electrocatalytic activity of compounds in oxygen electroreduction reaction on the surface of modified carbon paste electrode was evaluated.
Режим доступа: по договору с организацией-держателем ресурса
Ngôn ngữ:Tiếng Anh
Được phát hành: 2015
Những chủ đề:
Truy cập trực tuyến:http://dx.doi.org/10.1016/j.inoche.2015.01.024
Định dạng: Điện tử Chương của sách
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=639572