Synthesis, crystal structure and electrocatalytic activity of discrete and polymeric copper(II) complexes with bitopic bis(pyrazol-1-yl)methane ligands; Inorganic Chemistry Communications; Vol. 53

Synthesis, crystal structure and electrocatalytic activity of discrete and polymeric copper(II) complexes with bitopic bis(pyrazol-1-yl)methane ligands; Inorganic Chemistry Communications; Vol. 53

Bibliographic Details
Parent link:	Inorganic Chemistry Communications Vol. 53.— 2015.— [P. 72-75]
Corporate Author:	Национальный исследовательский Томский политехнический университет (ТПУ) Институт физики высоких технологий (ИФВТ) Кафедра биотехнологии и органической химии (БИОХ)
Other Authors:	Potapov A. S. Andrey Sergeevich, Nudnova E. A., Khlebnikov A. I. Andrey Ivanovich, Ogorodnikov V. D., Petrenko T. V.
Summary:	Title screen New coordination copper(II) compounds containing bitopic bis(pyrazol-1-yl)methane ligands, namely 1,1,2,2-tetrakis(pyrazol-1-yl)ethane, 1,4-bis[bis(pyrazol-1-yl)methyl]benzene and 1,4-bis[bis(3,5-dimethylpyrazol-1-yl)methyl]benzene were prepared. Reactions of ligands with Cu2 + ions in 1:2 ratio gave discrete homodinuclear complexes, while 1:1 ligand-to-metal ratio lead to the formation of coordination polymers. Electrocatalytic activity of compounds in oxygen electroreduction reaction on the surface of modified carbon paste electrode was evaluated. Режим доступа: по договору с организацией-держателем ресурса
Language:	English
Published:	2015
Subjects:	электронный ресурс труды учёных ТПУ Bis(pyrazol-1-yl)methane Copper(II) Bitopic ligands Coordination polymers Crystal structure Electrocatalytic activity
Online Access:	http://dx.doi.org/10.1016/j.inoche.2015.01.024
Format:	Electronic Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=639572

Internet

http://dx.doi.org/10.1016/j.inoche.2015.01.024