N-Hexane Bromination Using Barium Fluorobromate Ba(BrF[4])[2]
| Parent link: | Procedia Chemistry Vol. 10 : Chemistry and Chemical Engineering in XXI century.— 2014.— [P. 280-283] |
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| Corporate Authors: | , |
| Other Authors: | , , , , |
| Summary: | Title screen It was observed that Ba(BrF[4])[2] demonstrates a high reactivity towards n-hexane. It was found that the heating the reaction mass proceed with intensive self-heating up to 40 °C and release of elemental bromine. The GC-MS analysis showed that the main product of Ba(BrF[4])[2] interaction with n-hexane is 3-bromohexane. The optimal interaction parameters were found. The heat effect of the reaction was determined by isothermal calorimetric method, it was –1451 kJ/mole. The qualitative composition of solid precipitate was determined by EDXRF and XRD analyses. BaF[2] is formed as only solid product of the reaction between Ba(BrF[4])[2] and n-hexane. It was found that conditions of researched reaction are quite unusual for known free-radical hydrogen substitution processes in case of alkanes. Also we can conclude that Ba(BrF[4])[2] is much more soft reagent is case of interaction with alkanes in comparison with BrF[3] and it can provide more or less selective bromination of alkane unlikely to BrF[3]. Режим доступа: по договору с организацией-держателем ресурса |
| Language: | English |
| Published: |
2014
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| Subjects: | |
| Online Access: | http://dx.doi.org/10.1016/j.proche.2014.10.047 http://earchive.tpu.ru/handle/11683/35506 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=639503 |