Dicyclopentadiene Polymerization in Solutions under the Action of Various Catalytic Systems; Procedia Chemistry; Vol. 10 : Chemistry and Chemical Engineering in XXI century

Bibliografiske detaljer
Parent link:Procedia Chemistry
Vol. 10 : Chemistry and Chemical Engineering in XXI century.— 2014.— [P. 217-222]
Institution som forfatter: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра технологии органических веществ и полимерных материалов (ТОВПМ)
Andre forfattere: Lyapkov A. A. Aleksey Alekseevich, Gvozdkov E. L., Tarakanovskaya A. N., Tarnovskaya O. D., Yakovleva Y. S.
Summary:Title screen
The kinetics of dicyclopentadiene polymerization in toluene solution under the action of different catalytic systems through adiabatic thermometry was investigated. Unlike cationic metathesis polymerization has a sufficiently large induction period associated with low speed by implantation monomer on carbine bond of catalyst. It has been shown that the rate of metathesis polymerization of dicyclopentadiene in comparable circumstances is about three times lower than the rate of cationic polymerization of the same monomer.
Режим доступа: по договору с организацией-держателем ресурса
Sprog:engelsk
Udgivet: 2014
Fag:
Online adgang:http://dx.doi.org/10.1016/j.proche.2014.10.037
http://earchive.tpu.ru/handle/11683/35498
Format: Electronisk Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=639494
Beskrivelse
Summary:Title screen
The kinetics of dicyclopentadiene polymerization in toluene solution under the action of different catalytic systems through adiabatic thermometry was investigated. Unlike cationic metathesis polymerization has a sufficiently large induction period associated with low speed by implantation monomer on carbine bond of catalyst. It has been shown that the rate of metathesis polymerization of dicyclopentadiene in comparable circumstances is about three times lower than the rate of cationic polymerization of the same monomer.
Режим доступа: по договору с организацией-держателем ресурса
DOI:10.1016/j.proche.2014.10.037