Dicyclopentadiene Polymerization in Solutions under the Action of Various Catalytic Systems; Procedia Chemistry; Vol. 10 : Chemistry and Chemical Engineering in XXI century

Dicyclopentadiene Polymerization in Solutions under the Action of Various Catalytic Systems; Procedia Chemistry; Vol. 10 : Chemistry and Chemical Engineering in XXI century

Bibliographic Details
Parent link:Procedia Chemistry
Vol. 10 : Chemistry and Chemical Engineering in XXI century.— 2014.— [P. 217-222]
Corporate Author: Национальный исследовательский Томский политехнический университет (ТПУ) Институт природных ресурсов (ИПР) Кафедра технологии органических веществ и полимерных материалов (ТОВПМ)
Other Authors: Lyapkov A. A. Aleksey Alekseevich, Gvozdkov E. L., Tarakanovskaya A. N., Tarnovskaya O. D., Yakovleva Y. S.
Summary:Title screen
The kinetics of dicyclopentadiene polymerization in toluene solution under the action of different catalytic systems through adiabatic thermometry was investigated. Unlike cationic metathesis polymerization has a sufficiently large induction period associated with low speed by implantation monomer on carbine bond of catalyst. It has been shown that the rate of metathesis polymerization of dicyclopentadiene in comparable circumstances is about three times lower than the rate of cationic polymerization of the same monomer.
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2014
Subjects:
электронный ресурс
труды учёных ТПУ
полимеризация
дициклопентадиен
растворы
каталитические системы
катализаторы
тетрахлорид титана
адиабатические реакторы
термомеханические методы
константы
толуолы
catalytic polymerization
dicyclopentadiene
titanium tetrachloride
triisobuthylaluminum
original Hoveyda–Grubbs II type catalyst
adiabatic reactor
thermometric method
rates constants
Online Access:http://dx.doi.org/10.1016/j.proche.2014.10.037
http://earchive.tpu.ru/handle/11683/35498
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=639494

Internet

http://dx.doi.org/10.1016/j.proche.2014.10.037
http://earchive.tpu.ru/handle/11683/35498

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