Evaluation of the reactivity and regioselectivity of superelectrophilic iodinating systems; Russian Journal of Organic Chemistry; Vol. 45, iss. 9

Evaluation of the reactivity and regioselectivity of superelectrophilic iodinating systems; Russian Journal of Organic Chemistry; Vol. 45, iss. 9

Bibliographic Details
Parent link:Russian Journal of Organic Chemistry: Scientific Journal
Vol. 45, iss. 9.— 2009.— [P. 1349-1352]
Main Author: Chaikovskii V. K. Vitold Kazimirovich
Other Authors: Filimonov V. D. Viktor Dmitrievich, Funk A. A.
Summary:Title screen
Iodination of o-nitrotoluene in H2SO4 or CF3SO3H at 0°C with compounds having a nitrogen-iodine bond leads to the formation of isomeric mono- and diiodo derivatives whose ratio differs from the statistical value. The reaction of nitrobenzene with 2 equiv of N-I reagents in trifluoromethanesulfonic acid at 0°C takes less than 1 min and yields 79–85% of m-iodonitrobenzene. The electrophilic reactivity of the iodinating agents was estimated by quantum-chemical methods
Режим доступа: по договору с организацией-держателем ресурса
Language:English
Published: 2009
Subjects:
электронный ресурс
труды учёных ТПУ
Online Access:http://link.springer.com/article/10.1134/S1070428009090073
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=636564

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