Evaluation of the reactivity and regioselectivity of superelectrophilic iodinating systems
| Parent link: | Russian Journal of Organic Chemistry: Scientific Journal Vol. 45, iss. 9.— 2009.— [P. 1349-1352] |
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| Main Author: | |
| Other Authors: | , |
| Summary: | Title screen Iodination of o-nitrotoluene in H2SO4 or CF3SO3H at 0°C with compounds having a nitrogen-iodine bond leads to the formation of isomeric mono- and diiodo derivatives whose ratio differs from the statistical value. The reaction of nitrobenzene with 2 equiv of N-I reagents in trifluoromethanesulfonic acid at 0°C takes less than 1 min and yields 79–85% of m-iodonitrobenzene. The electrophilic reactivity of the iodinating agents was estimated by quantum-chemical methods Режим доступа: по договору с организацией-держателем ресурса |
| Language: | English |
| Published: |
2009
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| Subjects: | |
| Online Access: | http://link.springer.com/article/10.1134/S1070428009090073 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=636564 |