Study of electronic state of supported gold nanospecies by IR spectroscopy

Dades bibliogràfiques
Parent link:	The 7th International Forum on Strategic Technology (IFOST-2012), September 18-21, 2012, Tomsk: [proceedings]/ National Research Tomsk Polytechnic University (TPU). [4 p.].— , 2012
Altres autors:	Martynyuk O. A. Oksana Anatolievna, Pestryakov A. N. Aleksey Nikolaevich, Bogdanchikova N., Tiznado Н., Zepeda T. A., Tuzovskaya I.
Sumari:	Title screen The nature of different Au species supported on hexagonal mesoporous silica has been studied by infrared spectroscopy of adsorbed CO. Experiments revealed existence of the following states ofsupported gold: neutral metal particles Au°, ions Au+ and a number of partly charged states Auδ+ with different effective charge. Redox pretreatments (vacuum, O2 and H2) of Au/SiO2 at the different temperatures (100, 300 and 500°C) exert a significant effect on the electronic state of supported Au species. The experiments showed high stability of Auδ+ states under all treatments; that may prove their active role in catalytic properties of gold Режим доступа: по договору с организацией-держателем ресурса
Idioma:	anglès
Publicat:	2012
Matèries:	электронный ресурс труды учёных ТПУ gold catalyst mesoporous silica adsorption
Accés en línia:	http://dx.doi.org/10.1109/IFOST.2012.6357581
Format:	Electrònic Capítol de llibre
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=636296

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