Study of copper nanoparticles formation on supports of different nature by UV-Vis diffuse reflectance spectroscopy

Bibliographic Details
Parent link:Chemical physics letters.— , 1967-
Vol. 385, iss. 3-4.— 2004.— P. 173-176
Other Authors: Pestryakov A. N. Aleksey Nikolaevich, Petranovskii V. P., Kryazhov A., Ozhereliev O., Pfänder N., Knop-Gericke A.
Summary:Supported copper particles are widely used in heterogeneous catalysis. Influence of supports of different nature on the Cu particles formation is studied by the methods of UV-Vis spectroscopy of diffuse reflectance, XRD and electron microscopy. Different states of supported copper have been identified by UV-Vis spectroscopy: absorption bands at 250 (Cu+), 320-370 and 400-440 (charge transfer bands of O-Cu-O and Cu-O-Cu complexes), 520-580 (Cun plasmon resonance) and 620-850 nm (d-d transitions in Cu2+ ions). The size of Cu clusters and Cun/Cunδ+ ratio strongly depends on the support nature.
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Language:English
Published: 2004
Subjects:
Format: Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=599044