Unusually stable, versatile, and pure arenediazonium tosylates: Their preparation, structures, and synthetic applicability

Bibliographic Details
Parent link:Organic Letters.— , 1999-
Vol. 10, № 18.— 2008.— P. 3961-3964
Other Authors: Filimonov V. D. Viktor Dmitrievich, Trusova M., Postnikov P. S. Pavel Sergeevich, Krasnokutskaya E. A., Young Min Lee, Ho Yun Hwang, Hyunuk Kim, Ki Whan Chi
Summary:Graph Presented) A new, simple, and effective method for the diazotization of a wide range of arylamines has been developed by using a polymer-supported diazotization agent in the presence of p-toluenesulfonic acid. Various pure arenediazonium tosylates with unusual stabilities can be easily prepared by this method. As a result, these salts are useful and versatile substrates for subsequent transformations, such as halogenation and Heck-type reactions. The unusual stabilities of arenediazonium tosylates are also preliminarily discussed with their X-ray structures.
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Language:English
Published: 2008
Subjects:
Format: Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=596257