Investigation of isotopic composition of plasmachemical conversion products of sulfur hexafluoride

Bibliographic Details
Parent link:Bulletin of the Tomsk Polytechnic University/ Tomsk Polytechnic University (TPU).— , 2006-2007
Vol. 311, № 3.— 2007.— [P. 64-67]
Main Author: Sazonov R. V. Roman Vladimirovich
Other Authors: Pushkarev A. I. Aleksandr Ivanovich, Sosnovskiy S. A.
Summary:Заглавие с титульного листа
Электронная версия печатной публикации
The results of investigation of sulfur hexafluoride decomposition in mixture with hydrogen and oxygen in plasma of pulsed electron beam formed by accelerator TEA-500 (350...500 kV, 60 ns, current density 0,3...0,4 kA/cm2) have been presented. The data of thermodynamic simulation of gas mixture SF6+O2 and SF6+H2+O2 conversion in low-temperature plasma and gas mixture composition after electron beam influence measured by mass-spectrometer are given. It is shown that the formed gas-cycle compound synthesized in plasma of pulsed electron beam is sulfur difluoride-oxide. Isotope analysis of (SOF)+ and (SOF2)+ ions is carried out. It is obtained that sulfur isotope 34S content in sulfur difluoride-oxide exceeds its content in initial sulfur hexafluoride in 1,8±0,1 times
Published: 2007
Series:Chemistry
Subjects:
Online Access:http://www.lib.tpu.ru/fulltext/v/Bulletin_TPU/2007/v311eng/i3/16.pdf
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=182997