Ultralight, Mechanically Robust, and Flame-Retardant Polyimide/Silica Nanofibrous Sponges for Thermal Insulation; ACS Applied Materials & Interfaces; Vol. 18, iss. 18

Bibliographic Details
Parent link:ACS Applied Materials & Interfaces.— .— Washington: American Chemical Society
Vol. 18, iss. 18.— 2026.— P. 27099–27108
Corporate Author: Национальный исследовательский Томский политехнический университет Исследовательская школа химических и биомедицинских технологий
Other Authors: Lin Zeng, Zhao Huanyu, Zhang Xinxin, Surmenev R. A. Roman Anatolievich, Wang Sai, Yu Jianyong, Ding Bin
Summary:Title screen
The development of lightweight, flame-retardant thermal insulation materials capable of withstanding both extreme cold and potential fire hazards continues to be a significant challenge in the field of personal protective equipment. This study presents a facile method based on humidity-induced electrospinning to fabricate polyimide/silica (PI/SiO2) nanofibrous sponges (NFS) for high-performance thermal insulation. Regulating the rapid phase inversion within the whipping jet leads to the formation of a fluffy assembly of curly, porous nanofibers, and the PI nanofibrous sponge is further obtained following the imidization process. Furthermore, the introduction of nano-SiO2 particles creates a synergistic effect with the PI matrix at high temperature, promoting a dense, stable composite carbon layer that significantly improves flame retardancy. The final PI/SiO2–NFS exhibits ultralight property (2.77 mg cm–3), robust mechanical properties (withstand loads 10,000 times its own weight and remarkable elasticity and fatigue resistance), a low thermal conductivity (25.1 mW m–1 K–1), as well as outstanding flame retardancy. This work presents a novel pathway for developing next-generation high-performance thermal protection materials for personal safety in harsh environments
Текстовый файл
AM_Agreement
Language:English
Published: 2026
Subjects:
Online Access:https://doi.org/10.1021/acsami.6c05518
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=688430

MARC

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330 |a The development of lightweight, flame-retardant thermal insulation materials capable of withstanding both extreme cold and potential fire hazards continues to be a significant challenge in the field of personal protective equipment. This study presents a facile method based on humidity-induced electrospinning to fabricate polyimide/silica (PI/SiO2) nanofibrous sponges (NFS) for high-performance thermal insulation. Regulating the rapid phase inversion within the whipping jet leads to the formation of a fluffy assembly of curly, porous nanofibers, and the PI nanofibrous sponge is further obtained following the imidization process. Furthermore, the introduction of nano-SiO2 particles creates a synergistic effect with the PI matrix at high temperature, promoting a dense, stable composite carbon layer that significantly improves flame retardancy. The final PI/SiO2–NFS exhibits ultralight property (2.77 mg cm–3), robust mechanical properties (withstand loads 10,000 times its own weight and remarkable elasticity and fatigue resistance), a low thermal conductivity (25.1 mW m–1 K–1), as well as outstanding flame retardancy. This work presents a novel pathway for developing next-generation high-performance thermal protection materials for personal safety in harsh environments 
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