Preparation, structure, and reactivity of ortho-hydroxy-substituted aryliodonium salts, precursors to ortho-iodo-substituted diaryl ethers; Arkivoc; Vol. 4
| Parent link: | Arkivoc.— .— New-York: ARKAT USA, Inc. Vol. 4.— 2025.— Article number 202612556, 19 p. |
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| Weitere Verfasser: | , , , , , , , |
| Zusammenfassung: | Title screen ortho-Hydroxy-substituted aryliodonium salts were prepared by a two-step one-pot synthesis based on the reaction of 2-alkoxy-1-[(diacetoxy)iodo]arenes with arylboronic acids involving the initial formation of 2-alkoxyphenyl(aryl)iodonium salts and followed by deprotection of the intermediate product by boron tribromide. This procedure works well with halogen-, cyano-, 2-hydroxy-, 3-hydroxy-, 4-hydroxy-, methyl-, or trifluoromethyl-substituted arylboronic acids. Structures of three 2-hydroxyphenyl(aryl)iodonium bromides were confirmed by single crystal X-ray crystallography. The prepared 2-hydroxyphenyl(aryl)iodonium salts can be further converted to ortho-iodo-substituted diaryl ethers by treatment with a base via intermediate formation of the unstable aryliodonium betaines Текстовый файл |
| Sprache: | Englisch |
| Veröffentlicht: |
2025
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| Schlagworte: | |
| Online-Zugang: | https://doi.org/10.24820/ark.5550190.p012.556 |
| Format: | Elektronisch Buchkapitel |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=687712 |
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| 200 | 1 | |a Preparation, structure, and reactivity of ortho-hydroxy-substituted aryliodonium salts, precursors to ortho-iodo-substituted diaryl ethers |f M. S. Yusubov, A. Yoshimura, A. V. Lyulyaev [et al.] | |
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| 330 | |a ortho-Hydroxy-substituted aryliodonium salts were prepared by a two-step one-pot synthesis based on the reaction of 2-alkoxy-1-[(diacetoxy)iodo]arenes with arylboronic acids involving the initial formation of 2-alkoxyphenyl(aryl)iodonium salts and followed by deprotection of the intermediate product by boron tribromide. This procedure works well with halogen-, cyano-, 2-hydroxy-, 3-hydroxy-, 4-hydroxy-, methyl-, or trifluoromethyl-substituted arylboronic acids. Structures of three 2-hydroxyphenyl(aryl)iodonium bromides were confirmed by single crystal X-ray crystallography. The prepared 2-hydroxyphenyl(aryl)iodonium salts can be further converted to ortho-iodo-substituted diaryl ethers by treatment with a base via intermediate formation of the unstable aryliodonium betaines | ||
| 336 | |a Текстовый файл | ||
| 461 | 1 | |t Arkivoc |c New-York |n ARKAT USA, Inc. | |
| 463 | 1 | |t Vol. 4 |v Article number 202612556, 19 p. |d 2025 | |
| 610 | 1 | |a hypervalent iodine | |
| 610 | 1 | |a iodonium salts | |
| 610 | 1 | |a iodonium | |
| 610 | 1 | |a phenols | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 701 | 1 | |a Yusubov |b M. S. |c chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1961- |g Mekhman Suleiman-Ogly (Suleimanovich) |9 15928 | |
| 701 | 1 | |a Yoshimura |b A. |c chemical engineer |c Professor of Tomsk Polytechnic University |f 1981- |g Akira |9 21126 | |
| 701 | 1 | |a Lyulyaev |b A. V. |c biotechnologist |c Engineer of Tomsk Polytechnic University |f 2000- |g Aleksandr Vitaljevich |9 89339 | |
| 701 | 1 | |a Mironova |b I. A. |c chemist |c engineer of Tomsk Polytechnic University |f 1993- |g Irina Andreevna |9 20361 | |
| 701 | 1 | |a Shurikov |b M. K. |c Chemist |c Laboratory assistant of Tomsk Polytechnic University |f 2000- |g Matvey Konstantinovich |9 22267 | |
| 701 | 1 | |a Rode |b G. T. |g Gregori | |
| 701 | |a Saito Akio | ||
| 701 | 1 | |a Zhdankin |b V. V. |c chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1956- |g Viktor Vladimirovich |9 18915 | |
| 712 | 0 | 2 | |a Национальный исследовательский Томский политехнический университет |b Исследовательская школа химических и биомедицинских технологий |c (2017- ) |9 28334 |
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