The Role of Geometric Parameters of Palladium Nanoparticles in the Plasmon-Activated Suzuki–Miyaura Reaction; Russian Journal of General Chemistry; Vol. 96, iss. 4
| Parent link: | Russian Journal of General Chemistry.— .— New York: Springer Science+Business Media LLC. Vol. 96, iss. 4.— 2026.— Artcile number 70, 16 p. |
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| Autor Principal: | |
| Summary: | Title screen The role of nanoparticle shape in plasmon-activated processes was examined using the palladium-catalyzed Suzuki–Miyaura reaction. A series of cubic, icosahedral, and dodecahedral palladium nanoparticles, as well as their mixture in a defined ratio, was evaluated as plasmon-active substrates. As the number of edges and vertices of the nanoobjects in the catalytic system increased, the reaction proceeded more efficiently, giving higher yields of the target product. This effect is attributed to enhanced electric field generation at edges and vertices upon excitation of the surface plasmon. The quantitative predominance of low-coordination sites in plasmonic catalysis offers broad opportunities for developing efficient photocatalysts for energy conversion and chemical transformations AM_Agreement |
| Idioma: | inglés |
| Publicado: |
2026
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| Subjects: | |
| Acceso en liña: | https://doi.org/10.1134/S1070363225607513 |
| Formato: | Electrónico Capítulo de libro |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=687229 |
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| 330 | |a The role of nanoparticle shape in plasmon-activated processes was examined using the palladium-catalyzed Suzuki–Miyaura reaction. A series of cubic, icosahedral, and dodecahedral palladium nanoparticles, as well as their mixture in a defined ratio, was evaluated as plasmon-active substrates. As the number of edges and vertices of the nanoobjects in the catalytic system increased, the reaction proceeded more efficiently, giving higher yields of the target product. This effect is attributed to enhanced electric field generation at edges and vertices upon excitation of the surface plasmon. The quantitative predominance of low-coordination sites in plasmonic catalysis offers broad opportunities for developing efficient photocatalysts for energy conversion and chemical transformations | ||
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| 610 | 1 | |a Suzuki–Miyaura reaction | |
| 610 | 1 | |a surface plasmon resonance | |
| 700 | 1 | |a Votkina |b D. E. |c chemical engineer |c Associate Scientist of the Tomsk Polytechnic University |f 1995- |g Darjya Evgenjevna |9 21944 | |
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