Feather-like structures in oxidized ultrananocrystalline diamond films; Applied Physics Letters; Vol. 128, iss. 12

Detalles Bibliográficos
Parent link:Applied Physics Letters.— .— New York: AIP Publishing
Vol. 128, iss. 12.— 2026.— Article number 121908, 7 p.
Outros autores: Gaydaychuk A. V. Alexander Valerievich, Mitulinsky A. S. Aleksandr Sergeevich, Petrov I. S. Iljya Sergeevich, Zenkin S. P. Sergey Petrovich, Linnik S. A. Stepan Andreevich
Summary:Title screen
Ultrananocrystalline diamond films are conventionally described as diamond nanograins embedded in a sp2-rich amorphous carbon matrix. It was recently reported that as-deposited ultrananocrystalline diamond films consisted of dendrite-/nanofeather-like diamond aggregates embedded in a sp2-rich phase across the thickness. Here, we reveal that controlled oxidation at 725 °C selectively removes the intergranular sp2 phase, exposing the hierarchical architecture throughout the film thickness. Cross-sectional scanning electron microscopy and depth-resolved Raman spectroscopy support that this morphology originates during growth via intense secondary nucleation and constrained lateral crystallite expansion. These results challenge the grain matrix model and provide a scalable route to anisotropic, high-surface-area diamond coatings
Текстовый файл
AM_Agreement
Idioma:inglés
Publicado: 2026
Subjects:
Acceso en liña:https://doi.org/10.1063/5.0315144
Formato: Electrónico Capítulo de libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=686414

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200 1 |a Feather-like structures in oxidized ultrananocrystalline diamond films  |f Alexander Gaydaychuk, Alexander Mitulinsky, Ilia Petrov [et al.] 
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330 |a Ultrananocrystalline diamond films are conventionally described as diamond nanograins embedded in a sp2-rich amorphous carbon matrix. It was recently reported that as-deposited ultrananocrystalline diamond films consisted of dendrite-/nanofeather-like diamond aggregates embedded in a sp2-rich phase across the thickness. Here, we reveal that controlled oxidation at 725 °C selectively removes the intergranular sp2 phase, exposing the hierarchical architecture throughout the film thickness. Cross-sectional scanning electron microscopy and depth-resolved Raman spectroscopy support that this morphology originates during growth via intense secondary nucleation and constrained lateral crystallite expansion. These results challenge the grain matrix model and provide a scalable route to anisotropic, high-surface-area diamond coatings 
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461 1 |t Applied Physics Letters  |c New York  |n AIP Publishing 
463 1 |t Vol. 128, iss. 12  |v Article number 121908, 7 p.  |d 2026 
610 1 |a электронный ресурс 
610 1 |a труды учёных ТПУ 
610 1 |a diamond films 
610 1 |a electron microscopy 
610 1 |a nanomaterials 
610 1 |a oxidation 
701 1 |a Gaydaychuk  |b A. V.  |c physicist  |c Postgraduate, Engineer - Researcher of Tomsk Polytechnic University  |f 1984-  |g Alexander Valerievich  |9 16724 
701 1 |a Mitulinsky  |b A. S.  |c electric power specialist  |c technician of Tomsk Polytechnic University  |f 1998-  |g Aleksandr Sergeevich  |9 22706 
701 1 |a Petrov  |b I. S.  |c physicist, specialist in the field of nuclear technologies  |c Junior Researcher of the Tomsk Polytechnic University  |f 1994-  |g Iljya Sergeevich  |9 22501 
701 1 |a Zenkin  |b S. P.  |c physicist  |c Researcher of Tomsk Polytechnic University  |f 1988-  |g Sergey Petrovich  |9 21447 
701 1 |a Linnik  |b S. A.  |c physicist  |c Engineer-Researcher of Tomsk Polytechnic University  |f 1985-  |g Stepan Andreevich  |9 16725 
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