Regioselective deacetylation of peracetylated glycosides with a cleavable aglycone; Carbohydrate Research; Vol. 556
| Parent link: | Carbohydrate Research.— .— Amsterdam: Elsevier Science Publishing Company Inc. Vol. 556.— 2025.— Article number 109626, 8 p. |
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| অন্যান্য লেখক: | , , , , |
| সংক্ষিপ্ত: | Title screen Partially acetylated carbohydrates are integral to several biological functions and serve as synthetic intermediates for accessing complex glycoconjugates and oligosaccharides; however, their chemical synthesis remains highly challenging. Herein, we describe a straightforward protocol for the synthesis of monoacetylated sugars through acid-catalyzed regioselective deacetylation of readily accessible peracetylated glycosides featuring a cleavable aglycone (4-methoxyphenyl). The protocol proved effective for β-1,2-trans and α-1,2-cis-configured peracetylated pyranosides and its utility was demonstrated by large-scale synthesis, optimization for continuous flow, and application towards oligosaccharide synthesis Текстовый файл AM_Agreement |
| ভাষা: | ইংরেজি |
| প্রকাশিত: |
2025
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| বিষয়গুলি: | |
| অনলাইন ব্যবহার করুন: | https://doi.org/10.1016/j.carres.2025.109626 |
| বিন্যাস: | বৈদ্যুতিক গ্রন্থের অধ্যায় |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=685418 |