Short-Term Penetration beyond Diffusion Spinodal of a Mixture: Interaction of Liquid-Liquid and Liquid-Vapour Transitions; Frontiers in Heat and Mass Transfer; Vol. 23, iss. 3
| Parent link: | Frontiers in Heat and Mass Transfer.— .— Henderson: Tech Science Press (TSP) Vol. 23, iss. 3.— 2025.— P. 721-737 |
|---|---|
| अन्य लेखक: | , , , |
| सारांश: | Title screen The article considers a relaxation of the water/polypropylene glycol-425 solution with a lower critical solution temperature (LCST) following its pulsed superheating concerning liquid-liquid and liquid-vapor equilibrium lines, as well as the liquid-liquid spinodal. Superheating was performed using the pulsed heat generation method in a micro-sized wire probe. The main heating mode was the constant (over the pulse length) power mode. Characteristic heating rates ranged from 0.05 × 105 to 2 × 105 K/s, while the degree of superheating concerning the spinodal was up to 200 K. The temperature of spontaneous boiling-up and the amplitude of the corresponding signal were monitored as functions of the heating rate set by the power value. The results demonstrate an example of the interaction of liquid-liquid and liquid-vapor phase transitions, as well as the spinodal decomposition of a solution with LCST against the background of its unstable states. We proposed a physical model to explain the minimum spontaneous boiling-up temperature revealed within a certain range of heating rates, which is not typical of completely miscible solutions. Further research will focus on establishing a general criterion for the possibility of spinodal decomposition of such solutions under the conditions of rapid heating Текстовый файл AM_Agreement |
| भाषा: | अंग्रेज़ी |
| प्रकाशित: |
2025
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| विषय: | |
| ऑनलाइन पहुंच: | https://doi.org/10.32604/fhmt.2025.066528 |
| स्वरूप: | इलेक्ट्रोनिक पुस्तक अध्याय |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=685165 |
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