Formation of Value-Added Cyclic Carbonates by Coupling of Epoxides and CO2by Ruthenium Pincer Hydrazone Complexes under Atmospheric Pressure; Energy and Fuels; Vol. 37, iss. 3

Formation of Value-Added Cyclic Carbonates by Coupling of Epoxides and CO2by Ruthenium Pincer Hydrazone Complexes under Atmospheric Pressure; Energy and Fuels; Vol. 37, iss. 3

Bibliografski detalji
Parent link:	Energy and Fuels.— .— Washington: ACS Publications Vol. 37, iss. 3.— 2023.— P. 2178–2187
Daljnji autori:	Habib Ullah, Zakir Ullah, Khattak Z. A. K. Zafar, Mohsin Ali Marwat, Baoyi Yu, Hyung Wook Kwon, Hyun You Kim, Verpoort F. V. K. Frensis Valter Kornelius
Sažetak:	Title screen Transforming atmospheric CO2 into industrially valuable cyclic carbonates is of great importance and one of the attractive approaches for reducing CO2 concentration in the biosphere. However, the selectivity and conversion of ruthenium catalysts for cyclic carbonate formation via CO2 insertion to epoxides are low at high pressure. Here, a series of novel ruthenium complexes supported by ONN pincer-type hydrazone ligands were successfully generated, and their potential for CO2 valorization to cyclic carbonates was investigated. NMR, Fourier transform infrared (FT-IR), mass spectrometry, elemental analysis, and single-crystal diffraction analysis further confirmed the structures of these ruthenium compounds. These compounds were utilized for the CO2/coupling reaction after thorough characterization. Fortunately, these complexes outperform the reported ruthenium catalysts with a turn-over frequency of 833 h–1 and >99% selectivity at atmospheric pressure without any assisted cocatalyst. The designed catalyst showed consistent catalytic performance over five repeating cycles Текстовый файл AM_Agreement
Jezik:	engleski
Izdano:	2023
Teme:	электронный ресурс труды учёных ТПУ Catalysts Ethers Group 8 complexes Inorganic carbon compounds Ligands
Online pristup:	https://doi.org/10.1021/acs.energyfuels.2c03611
Format:	Elektronički Poglavlje knjige
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=685110

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