Molecular Plasmonic Silver Forests for the Photocatalytic-Driven Sensing Platforms; Nanomaterials; Vol. 13, iss. 5

Podrobná bibliografie
Parent link:Nanomaterials.— .— Basel: MDPI AG
Vol. 13, iss. 5.— 2023.— Article number 923, 11 p.
Další autoři: Fatkullin M. I. Maksim Ilgizovich, Rodriguez (Rodriges) Contreras R. D. Raul David, Petrov I. S. Iljya Sergeevich, Villa Pineda N. E. Nelson Enrrique, Lipovka A. A. Anna Anatolyevna, Gridina M. V. Mariya Vadimovna, Murastov G. V. Gennady Viktorovich, Chernova A. P. Anna Pavlovna, Plotnikov E. V. Evgeny Vladimirovich, Averkiev A. A. Andrey Alekseevich, Cheshev D. L. Dmitry Leonidovich, Semyonov O. V. Oleg Vladimirovich, Gubarev F. A. Fedor Aleksandrovich, Brazovsky (Brazovskii) K. S. Konstantin Stanislavovich, Sheng Wenbo, Sheremet E. S. Evgeniya Sergeevna
Shrnutí:Title screen
Structural electronics, as well as flexible and wearable devices are applications that are possible by merging polymers with metal nanoparticles. However, using conventional technologies, it is challenging to fabricate plasmonic structures that remain flexible. We developed three-dimensional (3D) plasmonic nanostructures/polymer sensors via single-step laser processing and further functionalization with 4-nitrobenzenethiol (4-NBT) as a molecular probe. These sensors allow ultrasensitive detection with surface-enhanced Raman spectroscopy (SERS). We tracked the 4-NBT plasmonic enhancement and changes in its vibrational spectrum under the chemical environment perturbations. As a model system, we investigated the sensor’s performance when exposed to prostate cancer cells’ media over 7 days showing the possibility of identifying the cell death reflected in the environment through the effects on the 4-NBT probe. Thus, the fabricated sensor could have an impact on the monitoring of the cancer treatment process. Moreover, the laser-driven nanoparticles/polymer intermixing resulted in a free-form electrically conductive composite that withstands over 1000 bending cycles without losing electrical properties. Our results bridge the gap between plasmonic sensing with SERS and flexible electronics in a scalable, energy-efficient, inexpensive, and environmentally friendly way
Текстовый файл
Jazyk:angličtina
Vydáno: 2023
Témata:
On-line přístup:https://doi.org/10.3390/nano13050923
Médium: xMaterials Elektronický zdroj Kapitola
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=685027

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200 1 |a Molecular Plasmonic Silver Forests for the Photocatalytic-Driven Sensing Platforms  |f Maxim Fatkullin, Raul D. Rodriguez, Ilia Petrov [et al.] 
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330 |a Structural electronics, as well as flexible and wearable devices are applications that are possible by merging polymers with metal nanoparticles. However, using conventional technologies, it is challenging to fabricate plasmonic structures that remain flexible. We developed three-dimensional (3D) plasmonic nanostructures/polymer sensors via single-step laser processing and further functionalization with 4-nitrobenzenethiol (4-NBT) as a molecular probe. These sensors allow ultrasensitive detection with surface-enhanced Raman spectroscopy (SERS). We tracked the 4-NBT plasmonic enhancement and changes in its vibrational spectrum under the chemical environment perturbations. As a model system, we investigated the sensor’s performance when exposed to prostate cancer cells’ media over 7 days showing the possibility of identifying the cell death reflected in the environment through the effects on the 4-NBT probe. Thus, the fabricated sensor could have an impact on the monitoring of the cancer treatment process. Moreover, the laser-driven nanoparticles/polymer intermixing resulted in a free-form electrically conductive composite that withstands over 1000 bending cycles without losing electrical properties. Our results bridge the gap between plasmonic sensing with SERS and flexible electronics in a scalable, energy-efficient, inexpensive, and environmentally friendly way 
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701 1 |a Fatkullin  |b M. I.  |c chemical engineer  |c Engineer of Tomsk Polytechnic University  |f 1997-  |g Maksim Ilgizovich  |9 22844 
701 1 |a Rodriguez (Rodriges) Contreras  |b R. D.  |c Venezuelan physicist, doctor of science  |c Professor of Tomsk Polytechnic University  |f 1982-  |g Raul David  |9 21179 
701 1 |a Petrov  |b I. S.  |c physicist, specialist in the field of nuclear technologies  |c Junior Researcher of the Tomsk Polytechnic University  |f 1994-  |g Iljya Sergeevich  |9 22501 
701 1 |a Villa Pineda  |b N. E.  |c chemical engineer  |c Engineer of Tomsk Polytechnic University  |f 1986-  |g Nelson Enrrique  |9 22846 
701 1 |a Lipovka  |b A. A.  |c chemist  |c Associate Scientist of Tomsk Polytechnic University  |f 1993-  |g Anna Anatolyevna  |9 21753 
701 1 |a Gridina  |b M. V.  |g Mariya Vadimovna 
701 1 |a Murastov  |b G. V.  |g Gennady Viktorovich 
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701 1 |a Plotnikov  |b E. V.  |c chemist  |c Associate Professor of Tomsk Polytechnic University, Candidate of Chemical Sciences  |f 1983-  |g Evgeny Vladimirovich  |9 16417 
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701 1 |a Cheshev  |b D. L.  |c Specialist in the field of material science  |c Engineer of Tomsk Polytechnic University  |f 2000-  |g Dmitry Leonidovich  |9 22924 
701 1 |a Semyonov  |b O. V.  |c process chemist  |c Junior Researcher, Tomsk Polytechnic University  |f 1993-  |g Oleg Vladimirovich  |9 21911 
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701 0 |a Sheng Wenbo 
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