Chromium–Lanthanide Complexes Containing the Cr═P═Cr Fragment: Synthesis, Characterization, and Computational Study; Inorganic Chemistry; Vol. 62, iss. 26

Chromium–Lanthanide Complexes Containing the Cr═P═Cr Fragment: Synthesis, Characterization, and Computational Study; Inorganic Chemistry; Vol. 62, iss. 26

Bibliographic Details
Parent link:Inorganic Chemistry.— .— Washington: ACS Publications
Vol. 62, iss. 26.— 2023.— P. 10110-10119
Other Authors: Afonin M. Yu. Mikhail Yurjevich, Konokhova A. Yu. Anastasiia, Dmitriev A. A. Alexey, Abramov P. A. Pavel Aleksandrovich, Kuratieva N. V. Natalia, Sukhikh T. S. Taisiya Sergeevna, Kompankov N. B. Nikolay, Gritsan N. Nina, Konchenko S. N. Sergey
Summary:Title screen
Reactions of HS-Arf (S–Arf = S–C6F5, S–C6F4–CF3) with AuI utilizing a new atom-economy method result in corresponding [Au(S–Arf)]n metal–organic coordination polymers, which were studied by DSC, SEM-EDX, TGA, IR, and PL. Treatment of these complexes with pyridine under mild conditions results in the transformation of the starting polymers into new [{Au(py)2}{Au(S–Arf)2}]n complexes of the polymeric structure, which were isolated and characterized by single-crystal X-ray diffraction (SCXRD). The linear [Au(py)2]+ cations combine with linear [Au(S–Arf)2]− anions via Au···Au interactions into infinite chains. Such interactions were studied by quantum-chemical calculations. Treatment of [Au(S–C6F4–CF3)]n with DMSO gives crystals of [Au4(S–C6F4–CF3)4]n·nDMSO that have a unique polymeric structure
Текстовый файл
AM_Agreement
Language:English
Published: 2023
Subjects:
электронный ресурс
труды учёных ТПУ
Online Access:https://doi.org/10.1021/acs.inorgchem.3c00518
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=684913

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