Chromium–Lanthanide Complexes Containing the Cr═P═Cr Fragment: Synthesis, Characterization, and Computational Study
| Parent link: | Inorganic Chemistry.— .— Washington: ACS Publications Vol. 62, iss. 26.— 2023.— P. 10110-10119 |
|---|---|
| Other Authors: | , , , , , , , , |
| Summary: | Title screen Reactions of HS-Arf (S–Arf = S–C6F5, S–C6F4–CF3) with AuI utilizing a new atom-economy method result in corresponding [Au(S–Arf)]n metal–organic coordination polymers, which were studied by DSC, SEM-EDX, TGA, IR, and PL. Treatment of these complexes with pyridine under mild conditions results in the transformation of the starting polymers into new [{Au(py)2}{Au(S–Arf)2}]n complexes of the polymeric structure, which were isolated and characterized by single-crystal X-ray diffraction (SCXRD). The linear [Au(py)2]+ cations combine with linear [Au(S–Arf)2]− anions via Au···Au interactions into infinite chains. Such interactions were studied by quantum-chemical calculations. Treatment of [Au(S–C6F4–CF3)]n with DMSO gives crystals of [Au4(S–C6F4–CF3)4]n·nDMSO that have a unique polymeric structure Текстовый файл AM_Agreement |
| Language: | English |
| Published: |
2023
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| Subjects: | |
| Online Access: | https://doi.org/10.1021/acs.inorgchem.3c00518 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=684913 |
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| 200 | 1 | |a Chromium–Lanthanide Complexes Containing the Cr═P═Cr Fragment: Synthesis, Characterization, and Computational Study |f M. Yu. Afonin, A. Yu. Konokhova, A. A. Dmitriev [et al.] | |
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| 300 | |a Title screen | ||
| 320 | |a References: 56 tit | ||
| 330 | |a Reactions of HS-Arf (S–Arf = S–C6F5, S–C6F4–CF3) with AuI utilizing a new atom-economy method result in corresponding [Au(S–Arf)]n metal–organic coordination polymers, which were studied by DSC, SEM-EDX, TGA, IR, and PL. Treatment of these complexes with pyridine under mild conditions results in the transformation of the starting polymers into new [{Au(py)2}{Au(S–Arf)2}]n complexes of the polymeric structure, which were isolated and characterized by single-crystal X-ray diffraction (SCXRD). The linear [Au(py)2]+ cations combine with linear [Au(S–Arf)2]− anions via Au···Au interactions into infinite chains. Such interactions were studied by quantum-chemical calculations. Treatment of [Au(S–C6F4–CF3)]n with DMSO gives crystals of [Au4(S–C6F4–CF3)4]n·nDMSO that have a unique polymeric structure | ||
| 336 | |a Текстовый файл | ||
| 371 | 0 | |a AM_Agreement | |
| 461 | 1 | |t Inorganic Chemistry |c Washington |n ACS Publications | |
| 463 | 1 | |t Vol. 62, iss. 26 |v P. 10110-10119 |d 2023 | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 701 | 1 | |a Afonin |b M. Yu. |g Mikhail Yurjevich | |
| 701 | 1 | |a Konokhova |b A. Yu. |g Anastasiia | |
| 701 | 1 | |a Dmitriev |b A. A. |g Alexey | |
| 701 | 1 | |a Abramov |b P. A. |c chemist |c professor, senior researcher at Tomsk Polytechnic University, Doctor of Chemical Sciences |f 1985- |g Pavel Aleksandrovich |9 88582 | |
| 701 | 1 | |a Kuratieva |b N. V. |g Natalia | |
| 701 | 1 | |a Sukhikh |b T. S. |g Taisiya Sergeevna | |
| 701 | 1 | |a Kompankov |b N. B. |g Nikolay | |
| 701 | 1 | |a Gritsan |b N. |g Nina | |
| 701 | 1 | |a Konchenko |b S. N. |g Sergey | |
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