[Au(S–C6F5)] and [Au(S–C6F4–CF3)]: Reactivity, Structure, DSC, and Calculation Studies; Inorganic Chemistry; Vol. 64, iss. 43

[Au(S–C6F5)] and [Au(S–C6F4–CF3)]: Reactivity, Structure, DSC, and Calculation Studies; Inorganic Chemistry; Vol. 64, iss. 43

Manylion Llyfryddiaeth
Parent link:Inorganic Chemistry.— .— Washington: ACS Publications
Vol. 64, iss. 43.— 2025.— P. 21772-21780
Awduron Eraill: Tkachenko P. Pavel, Maksimov A. M. Aleksandr Mikhaylovich, Sinitsa V. Varvara, Sulyaeva V. S. Veronica, Pishchur D. A. Denis, Plyusnin P. E. Pavel, Berezin A. S. Aleksey Sergeevich, Sukhikh T. S. Taisiya, Sokolov M. N. Maxim, Abramov P. A. Pavel Aleksandrovich
Crynodeb:Title screen
Reactions of HS-Arf (S–Arf = S–C6F5, S–C6F4–CF3) with AuI utilizing a new atom-economy method result in corresponding [Au(S–Arf)]n metal–organic coordination polymers, which were studied by DSC, SEM-EDX, TGA, IR, and PL. Treatment of these complexes with pyridine under mild conditions results in the transformation of the starting polymers into new [{Au(py)2}{Au(S–Arf)2}]n complexes of the polymeric structure, which were isolated and characterized by single-crystal X-ray diffraction (SCXRD). The linear [Au(py)2]+ cations combine with linear [Au(S–Arf)2]− anions via Au···Au interactions into infinite chains. Such interactions were studied by quantum-chemical calculations. Treatment of [Au(S–C6F4–CF3)]n with DMSO gives crystals of [Au4(S–C6F4–CF3)4]n·nDMSO that have a unique polymeric structure
Текстовый файл
AM_Agreement
Iaith:Saesneg
Cyhoeddwyd: 2025
Pynciau:
Two-dimensional iodine
Differential scanning calorimetry
Gold
Ligands
Metals
Thiolates
электронный ресурс
труды учёных ТПУ
Mynediad Ar-lein:https://doi.org/10.1021/acs.inorgchem.5c04455
Fformat: Electronig Pennod Llyfr
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=684870

Eitemau Tebyg

Eitemau Tebyg