[Au(S–C6F5)] and [Au(S–C6F4–CF3)]: Reactivity, Structure, DSC, and Calculation Studies
| Parent link: | Inorganic Chemistry.— .— Washington: ACS Publications Vol. 64, iss. 43.— 2025.— P. 21772-21780 |
|---|---|
| Other Authors: | , , , , , , , , , |
| Summary: | Title screen Reactions of HS-Arf (S–Arf = S–C6F5, S–C6F4–CF3) with AuI utilizing a new atom-economy method result in corresponding [Au(S–Arf)]n metal–organic coordination polymers, which were studied by DSC, SEM-EDX, TGA, IR, and PL. Treatment of these complexes with pyridine under mild conditions results in the transformation of the starting polymers into new [{Au(py)2}{Au(S–Arf)2}]n complexes of the polymeric structure, which were isolated and characterized by single-crystal X-ray diffraction (SCXRD). The linear [Au(py)2]+ cations combine with linear [Au(S–Arf)2]− anions via Au···Au interactions into infinite chains. Such interactions were studied by quantum-chemical calculations. Treatment of [Au(S–C6F4–CF3)]n with DMSO gives crystals of [Au4(S–C6F4–CF3)4]n·nDMSO that have a unique polymeric structure Текстовый файл AM_Agreement |
| Language: | English |
| Published: |
2025
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| Subjects: | |
| Online Access: | https://doi.org/10.1021/acs.inorgchem.5c04455 |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=684870 |
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| 200 | 1 | |a [Au(S–C6F5)] and [Au(S–C6F4–CF3)]: Reactivity, Structure, DSC, and Calculation Studies |f P. A. Tkachenko, A. M. Maksimov, V. Sinitsa [et al.] | |
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| 300 | |a Title screen | ||
| 320 | |a References: 73 tit | ||
| 330 | |a Reactions of HS-Arf (S–Arf = S–C6F5, S–C6F4–CF3) with AuI utilizing a new atom-economy method result in corresponding [Au(S–Arf)]n metal–organic coordination polymers, which were studied by DSC, SEM-EDX, TGA, IR, and PL. Treatment of these complexes with pyridine under mild conditions results in the transformation of the starting polymers into new [{Au(py)2}{Au(S–Arf)2}]n complexes of the polymeric structure, which were isolated and characterized by single-crystal X-ray diffraction (SCXRD). The linear [Au(py)2]+ cations combine with linear [Au(S–Arf)2]− anions via Au···Au interactions into infinite chains. Such interactions were studied by quantum-chemical calculations. Treatment of [Au(S–C6F4–CF3)]n with DMSO gives crystals of [Au4(S–C6F4–CF3)4]n·nDMSO that have a unique polymeric structure | ||
| 336 | |a Текстовый файл | ||
| 371 | 0 | |a AM_Agreement | |
| 461 | 1 | |t Inorganic Chemistry |c Washington |n ACS Publications | |
| 463 | 1 | |t Vol. 64, iss. 43 |v P. 21772-21780 |d 2025 | |
| 610 | 1 | |a Two-dimensional iodine | |
| 610 | 1 | |a Differential scanning calorimetry | |
| 610 | 1 | |a Gold | |
| 610 | 1 | |a Ligands | |
| 610 | 1 | |a Metals | |
| 610 | 1 | |a Thiolates | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 701 | 1 | |a Tkachenko |b P. |g Pavel | |
| 701 | 1 | |a Maksimov |b A. M. |g Aleksandr Mikhaylovich | |
| 701 | 1 | |a Sinitsa |b V. |g Varvara | |
| 701 | 1 | |a Sulyaeva |b V. S. |g Veronica | |
| 701 | 1 | |a Pishchur |b D. A. |g Denis | |
| 701 | 1 | |a Plyusnin |b P. E. |g Pavel | |
| 701 | 1 | |a Berezin |b A. S. |g Aleksey Sergeevich | |
| 701 | 1 | |a Sukhikh |b T. S. |g Taisiya | |
| 701 | 1 | |a Sokolov |b M. N. |g Maxim | |
| 701 | 1 | |a Abramov |b P. A. |c chemist |c professor, senior researcher at Tomsk Polytechnic University, Doctor of Chemical Sciences |f 1985- |g Pavel Aleksandrovich |9 88582 | |
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