Synthesis, Crystal Structure, and Luminescent Properties of Ni(II), Zn(II), and Cd(II) Coordination Compounds with 1-(5-methyl-1H-pyrazol-3-yl)-1,2,3-Triazole-4-Carboxylic Acid

Synthesis, Crystal Structure, and Luminescent Properties of Ni(II), Zn(II), and Cd(II) Coordination Compounds with 1-(5-methyl-1H-pyrazol-3-yl)-1,2,3-Triazole-4-Carboxylic Acid

Bibliografiske detaljer
Parent link:	Journal of Structural Chemistry.— .— New York: Springer Science+Business Media LLC. Vol. 66, iss. 10.— 2025.— P. 2239-2249
Andre forfattere:	Osipov A. V., Estaeva M. Makpal, Pavlov D. I. Dmitry Igorevich, Ryadun A. A., Krasnokutskaya E. A . Elena Aleksandrovna, Potapov A. S. Andrey Sergeevich
Summary:	Title screen New coordination Ni(II), Zn(II), and Cd(II) compounds with 1-(5-methyl-1H-pyrazol-3-yl)-1,2,3-triazole-4-carboxylic acid (H2L) are prepared and characterized. It is established by SCXRD that [Ni(HL)2(H2O)2]·2H2O and [Zn(HL)2(H2O)2]·2H2O are isostructural discrete complexes with a ligand coordinated in the N,O-bidentate chelate mode. A [Zn(HL)2]n 1D metal-organic framework with bridging carboxylate groups is prepared by changing the synthesis conditions. The interaction of H2L with cadmium perchlorate leads to the formation of the [Cd(HL2]n layered 2D metal-organic framework bearing a ligand coordinated in the N,O,O-tridentate mode via the pyrazole ring′s nitrogen atom and the bridging carboxylate group. The cadmium coordination polymer exhibits two-band luminescence with maxima at 460 nm and 530 nm Текстовый файл AM_Agreement
Udgivet:	2025
Fag:	nickel zinc cadmium coordination compound metal-organic frameworks luminescence pyrazole 1,2,3-triazole carboxylate ligands электронный ресурс труды учёных ТПУ
Online adgang:	https://doi.org/10.1134/S002247662510021X
Format:	Electronisk Book Chapter
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=684189

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