Study of Physicochemical Properties of Feedstock and Product in the Technology of Linear Alkylbenzene Sulfonation; Petroleum and Coal; Vol. 67, iss. 4

Podrobná bibliografie
Parent link:Petroleum and Coal.— .— Bratislava: Slovnaft VURUP
Vol. 67, iss. 4.— 2025.— P. 1044-1049
Další autoři: Ivashkina E. N. Elena Nikolaevna, Krivtsova N. I. Nadezhda Igorevna, Dolganova I. O. Irena Olegovna, Dolganov I. M. Igor Mikhailovich, Matkova A. E. Anna Evgenjevna
Shrnutí:Title screen
The study investigates the sulfonation process of linear alkylbenzene (LAB) using SO3 to produce alkylbenzene sulfonic acid (ABSA), a key intermediate in surfactant manufacturing. Three industrial AB samples and one ABSA product were analyzed to evaluate their physicochemical properties, including density, viscosity, water content, and isomeric composition. The quality of AB was assessed using gas chromatography–mass spectrometry (GC-MS), and the resulting ABSA was evaluated for sulfonic acid content, sulfuric acid concentration, unsulfonated compounds, and color index. Analytical techniques included Stabinger viscometry (SVM 4001), Shatox water analyzers, and titrimetric methods. Experimental results showed that only one of the three AB samples met the required specifications and was suitable for sulfonation. ABSA properties were found to be within acceptable industrial limits, although slight deviations in non-sulfonated matter were observed. The study provides a validated methodology for feedstock selection and product quality monitoring, supporting future development of industrial process optimization and mathematical modeling
Текстовый файл
Jazyk:angličtina
Vydáno: 2025
Témata:
On-line přístup:https://www.vurup.sk/wp-content/uploads/2025/11/PC-X_Dolganova_2025_103.pdf
Médium: Elektronický zdroj Kapitola
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=683624

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200 1 |a Study of Physicochemical Properties of Feedstock and Product in the Technology of Linear Alkylbenzene Sulfonation  |f Elena N. Ivashkina, Nadezhda I. Krivtcova, Irena O. Dolganova [et al.] 
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330 |a The study investigates the sulfonation process of linear alkylbenzene (LAB) using SO3 to produce alkylbenzene sulfonic acid (ABSA), a key intermediate in surfactant manufacturing. Three industrial AB samples and one ABSA product were analyzed to evaluate their physicochemical properties, including density, viscosity, water content, and isomeric composition. The quality of AB was assessed using gas chromatography–mass spectrometry (GC-MS), and the resulting ABSA was evaluated for sulfonic acid content, sulfuric acid concentration, unsulfonated compounds, and color index. Analytical techniques included Stabinger viscometry (SVM 4001), Shatox water analyzers, and titrimetric methods. Experimental results showed that only one of the three AB samples met the required specifications and was suitable for sulfonation. ABSA properties were found to be within acceptable industrial limits, although slight deviations in non-sulfonated matter were observed. The study provides a validated methodology for feedstock selection and product quality monitoring, supporting future development of industrial process optimization and mathematical modeling 
336 |a Текстовый файл 
461 1 |t Petroleum and Coal  |c Bratislava  |n Slovnaft VURUP 
463 1 |t Vol. 67, iss. 4  |v P. 1044-1049  |d 2025 
610 1 |a Sulfonation 
610 1 |a Linear alkylbenzene 
610 1 |a Alkylbenzenesulfonic acid 
610 1 |a Coloring products 
610 1 |a Mathematical modeling 
610 1 |a электронный ресурс 
610 1 |a труды учёных ТПУ 
701 1 |a Ivashkina  |b E. N.  |c Chemical Engineer  |c Professor of Tomsk Polytechnic University, Doctor of technical sciences  |f 1983-  |g Elena Nikolaevna  |9 15453 
701 1 |a Krivtsova  |b N. I.  |c Chemical Engineer  |c Associate Professor of Tomsk Polytechnic University, Candidate of technical sciences  |f 1983-  |g Nadezhda Igorevna  |9 17476 
701 1 |a Dolganova  |b I. O.  |c chemist  |c Associate Scientist of Tomsk Polytechnic University, postgraduate student, candidate of technical Sciences  |f 1988-  |g Irena Olegovna  |9 15449 
701 1 |a Dolganov  |b I. M.  |c Chemical Engineer  |c Associate Professor of Tomsk Polytechnic University, Candidate of Technical Sciences  |f 1987-  |g Igor Mikhailovich  |9 16216 
701 1 |a Matkova  |b A. E.  |g Anna Evgenjevna 
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