Luminescent ceramic materials based on laser-synthesized europium-stabilized zirconia nanopowders; Ceramics International; Vol. 52, iss. 29, pt. B

Bibliographic Details
Parent link:Ceramics International.— .— Amsterdam: Elsevier Science Publishing Company Inc.
Vol. 52, iss. 29, pt. B.— 2025.— С. 60897-60907
Other Authors: Paygin V. D. Vladimir Denisovich, Kostyukov A. I. Anton Ivanovich, Morkhova E. A. Elizaveta Aleksandrovna, Deulina D. E. Darjya Evgenjevna, Nashivochnikov A., Suprun E. A. Evgeniy Aleksandrovich, Dvilis E. S. Edgar Sergeevich
Summary:ZrO2-based materials are considered the gold standard for the manufacturing of ceramic materials used in various applications. Spark plasma sintering has been successfully applied to the fabrication of europium-stabilized zirconia (ESZ) ceramic materials from nanopowders synthesized by laser vaporization. Structural, morphological (XRD and SEM), mechanical, and spectroscopic (photoluminescence) analysis have been used to investigate the influence of the stabilizer (Eu3+) content on ceramics phase composition, crystallite size, relative density, mechanical, and luminescent properties of the ESZ-ceramic materials. The theoretical analysis of the conductive properties of europium-stabilized zirconia with varying Eu concentrations has been conducted. To achieve this, a fast geometrical-topological (GT) method, the bond valence site energy (BVSE) approach, and kinetic Monte Carlo simulation were used. It has been shown that the initial nanostructured ESZ powders have high purity, an average particle size from 11 to 14 nm, agglomerate sizes from 171 to 458 nm, and a specific surface area from 70.11 to 84.85 m2g-1. It has been found that powders, prepared by the laser vaporization method, are of practical interest for manufacturing ESZ-ceramic materials without the use of additional stabilizing additives or activators and can be considered potential promising materials for luminescent applications, such as luminescence sensors, light sources, biotechnology and as solid electrolyte due to its conductive properties
Текстовый файл
AM_Agreement
Language:English
Published: 2025
Subjects:
Online Access:https://doi.org/10.1016/j.ceramint.2025.10.284
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=683316

MARC

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330 |a ZrO2-based materials are considered the gold standard for the manufacturing of ceramic materials used in various applications. Spark plasma sintering has been successfully applied to the fabrication of europium-stabilized zirconia (ESZ) ceramic materials from nanopowders synthesized by laser vaporization. Structural, morphological (XRD and SEM), mechanical, and spectroscopic (photoluminescence) analysis have been used to investigate the influence of the stabilizer (Eu3+) content on ceramics phase composition, crystallite size, relative density, mechanical, and luminescent properties of the ESZ-ceramic materials. The theoretical analysis of the conductive properties of europium-stabilized zirconia with varying Eu concentrations has been conducted. To achieve this, a fast geometrical-topological (GT) method, the bond valence site energy (BVSE) approach, and kinetic Monte Carlo simulation were used. It has been shown that the initial nanostructured ESZ powders have high purity, an average particle size from 11 to 14 nm, agglomerate sizes from 171 to 458 nm, and a specific surface area from 70.11 to 84.85 m2g-1. It has been found that powders, prepared by the laser vaporization method, are of practical interest for manufacturing ESZ-ceramic materials without the use of additional stabilizing additives or activators and can be considered potential promising materials for luminescent applications, such as luminescence sensors, light sources, biotechnology and as solid electrolyte due to its conductive properties 
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461 1 |t Ceramics International  |c Amsterdam  |n Elsevier Science Publishing Company Inc. 
463 1 |t Vol. 52, iss. 29, pt. B  |v С. 60897-60907  |d 2025 
610 1 |a Zirconia 
610 1 |a Europium-stabilized zirconia 
610 1 |a Spark plasma sintering 
610 1 |a Luminescent ceramics 
610 1 |a Laser vaporization 
610 1 |a Europium ions 
610 1 |a труды учёных ТПУ 
610 1 |a электронный ресурс 
701 1 |a Paygin  |b V. D.  |c specialist in the field of material science  |c engineer of Tomsk Polytechnic University  |f 1992-  |g Vladimir Denisovich  |9 20806 
701 1 |a Kostyukov  |b A. I.  |g Anton Ivanovich 
701 1 |a Morkhova  |b E. A.  |g Elizaveta Aleksandrovna 
701 1 |a Deulina  |b D. E.  |c specialist in the field of material science  |c Research Engineer of Tomsk Polytechnic University  |f 1999-  |g Darjya Evgenjevna  |9 88618 
701 1 |a Nashivochnikov  |b A. 
701 1 |a Suprun  |b E. A.  |g Evgeniy Aleksandrovich 
701 1 |a Dvilis  |b E. S.  |c Chemical Engineer  |c senior researcher of Tomsk Polytechnic University, Professor, doctor of physical and mathematical Sciences  |f 1969-  |g Edgar Sergeevich  |9 17959 
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