Strategic Synthesis and Supramolecular Organization of Arylenebis(aryliodonium) Salts; Journal of Organic Chemistry; Vol. 90, iss.44

Strategic Synthesis and Supramolecular Organization of Arylenebis(aryliodonium) Salts; Journal of Organic Chemistry; Vol. 90, iss.44

Bibliographic Details
Parent link:Journal of Organic Chemistry.— .— Washington: American Chemical Society
Vol. 90, iss.44.— 2025.— P. 15542-15554
Other Authors: Knyazeva E. V. Elizaveta Vyacheslavovna, Soldatova N. S. Nataliya Sergeevna, Abramov P. A. Pavel Aleksandrovich, Ivanov D. M. Daniil Mikhaylovich, Burykina Ju. V. Julia, Radzhabov A. D. Amirbek Dzhurabekovich, Yusubov M. S. Mekhman Suleiman-Ogly (Suleimanovich), Resnati D. P. Dzhuzeppe Paolo, Kukushkin V. Yu. Vadim Yurjevich, Postnikov P. S. Pavel Sergeevich
Summary:Title screen
A comprehensive synthetic toolkit was developed for the preparation of arylenebis(aryliodonium) salts from diiodoarenes via m-CPBA oxidation. The methodology offers versatile approaches that can be adapted based on the solubility of reaction intermediates, enabling either one-pot or two-stage synthesis pathways. Four distinct synthetic methods were established, accommodating a wide range of arenes and diiodoarenes, including sterically hindered and electron-deficient substrates. The resulting bis(iodonium) salts were isolated in good to excellent yields (up to 99%). X-ray crystallographic analysis of these compounds revealed intriguing supramolecular organization in the solid state, with the formation of 1D chains through halogen bonding interactions. These self-assembled architectures demonstrate the potential of bis(iodonium) cations as valuable building blocks for applications in crystal engineering
Текстовый файл
Language:English
Published: 2025
Subjects:
электронный ресурс
труды учёных ТПУ
Online Access:https://doi.org/10.1021/acs.joc.5c01508
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=683111

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