Strategic Synthesis and Supramolecular Organization of Arylenebis(aryliodonium) Salts; Journal of Organic Chemistry; Vol. 90, iss.44
| Parent link: | Journal of Organic Chemistry.— .— Washington: American Chemical Society Vol. 90, iss.44.— 2025.— P. 15542-15554 |
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| Rannpháirtithe: | , , , , , , , , , |
| Achoimre: | Title screen A comprehensive synthetic toolkit was developed for the preparation of arylenebis(aryliodonium) salts from diiodoarenes via m-CPBA oxidation. The methodology offers versatile approaches that can be adapted based on the solubility of reaction intermediates, enabling either one-pot or two-stage synthesis pathways. Four distinct synthetic methods were established, accommodating a wide range of arenes and diiodoarenes, including sterically hindered and electron-deficient substrates. The resulting bis(iodonium) salts were isolated in good to excellent yields (up to 99%). X-ray crystallographic analysis of these compounds revealed intriguing supramolecular organization in the solid state, with the formation of 1D chains through halogen bonding interactions. These self-assembled architectures demonstrate the potential of bis(iodonium) cations as valuable building blocks for applications in crystal engineering Текстовый файл |
| Teanga: | Béarla |
| Foilsithe / Cruthaithe: |
2025
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| Ábhair: | |
| Rochtain ar líne: | https://doi.org/10.1021/acs.joc.5c01508 |
| Formáid: | Leictreonach Caibidil leabhair |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=683111 |
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| 200 | 1 | |a Strategic Synthesis and Supramolecular Organization of Arylenebis(aryliodonium) Salts |f Elizaveta V. Knyazeva, Natalia S. Soldatova, Pavel A. Abramov [et al.] | |
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| 330 | |a A comprehensive synthetic toolkit was developed for the preparation of arylenebis(aryliodonium) salts from diiodoarenes via m-CPBA oxidation. The methodology offers versatile approaches that can be adapted based on the solubility of reaction intermediates, enabling either one-pot or two-stage synthesis pathways. Four distinct synthetic methods were established, accommodating a wide range of arenes and diiodoarenes, including sterically hindered and electron-deficient substrates. The resulting bis(iodonium) salts were isolated in good to excellent yields (up to 99%). X-ray crystallographic analysis of these compounds revealed intriguing supramolecular organization in the solid state, with the formation of 1D chains through halogen bonding interactions. These self-assembled architectures demonstrate the potential of bis(iodonium) cations as valuable building blocks for applications in crystal engineering | ||
| 336 | |a Текстовый файл | ||
| 461 | 1 | |t Journal of Organic Chemistry |c Washington |n American Chemical Society | |
| 463 | 1 | |t Vol. 90, iss.44 |v P. 15542-15554 |d 2025 | |
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| 701 | 1 | |a Soldatova |b N. S. |c organic chemist |c engineer of Tomsk Polytechnic University |f 1992- |g Nataliya Sergeevna |9 19363 | |
| 701 | 1 | |a Abramov |b P. A. |c chemist |c professor, senior researcher at Tomsk Polytechnic University, Doctor of Chemical Sciences |f 1985- |g Pavel Aleksandrovich |9 88582 | |
| 701 | 1 | |a Ivanov |b D. M. |c Chemist |c Senior researcher of Tomsk Polytechnic University, Candidate of chemical sciences |f 1992- |g Daniil Mikhaylovich |9 22632 | |
| 701 | 1 | |a Burykina |b Ju. V. |g Julia | |
| 701 | 1 | |a Radzhabov |b A. D. |c chemical technologist |c Junior Researcher at Tomsk Polytechnic University |f 1997- |g Amirbek Dzhurabekovich |9 88552 | |
| 701 | 1 | |a Yusubov |b M. S. |c chemist |c Professor of Tomsk Polytechnic University, Doctor of chemical sciences |f 1961- |g Mekhman Suleiman-Ogly (Suleimanovich) |9 15928 | |
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| 701 | 1 | |a Kukushkin |b V. Yu. |g Vadim Yurjevich | |
| 701 | 1 | |a Postnikov |b P. S. |c organic chemist |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences |f 1984- |g Pavel Sergeevich |9 15465 | |
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