Electrospun Nanomembrane-Assisted Transesterification for Biodiesel Production; Industrial & Engineering Chemistry Research; Vol. 64, iss. 27

Podrobná bibliografie
Parent link:Industrial & Engineering Chemistry Research.— .— Washington: ACS Publications
Vol. 64, iss. 27.— 2025.— P. 13795-13810
Další autoři: Piskunova A. E. Aleksandra Evgenjevna, Khomutov N. A. Nikita Andreevich, Ashikhmin A. E. Alexander Evgenjevich, Chobotova V. M. Vladlena Mikhaylovna, Di Martino A. Antonio, Melnik E. Yu. Evgeniy Yurjevich, Bolbasov E. N. Evgeny Nikolaevich, Piskunov M. V. Maksim Vladimirovich, Strizhak P. A. Pavel Alexandrovich
Shrnutí:Title screen
The study examines how well a nanomembrane reactor functions in the base catalyst transesterification process to produce biodiesel with rapeseed oil as the feedstock. The fabrication of a porous electrospun nanomembrane was achieved through the utilization of poly(vinylidene fluoride) and a copolymer of vinylidene fluoride with tetrafluoroethylene. The polymeric membrane’s structure allowed it to passively filter the crude biodiesel produced while retaining the glycerol and byproducts. With the maximum fatty acid methyl esters (FAME) content of about 99% and high reproducibility, the ideal transesterification conditions were found at 65 °C and a 4:1 methanol/oil weight ratio for 65 min. The FAME produced satisfied the key requirements of EN 14214. After four preparation cycles, there was no glycerol in the product stream, indicating that the nanomembrane could hold the glycerol in the reaction medium
Текстовый файл
AM_Agreement
Jazyk:angličtina
Vydáno: 2025
Témata:
On-line přístup:https://doi.org/10.1021/acs.iecr.5c01016
Médium: MixedMaterials Elektronický zdroj Kapitola
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=682668

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330 |a The study examines how well a nanomembrane reactor functions in the base catalyst transesterification process to produce biodiesel with rapeseed oil as the feedstock. The fabrication of a porous electrospun nanomembrane was achieved through the utilization of poly(vinylidene fluoride) and a copolymer of vinylidene fluoride with tetrafluoroethylene. The polymeric membrane’s structure allowed it to passively filter the crude biodiesel produced while retaining the glycerol and byproducts. With the maximum fatty acid methyl esters (FAME) content of about 99% and high reproducibility, the ideal transesterification conditions were found at 65 °C and a 4:1 methanol/oil weight ratio for 65 min. The FAME produced satisfied the key requirements of EN 14214. After four preparation cycles, there was no glycerol in the product stream, indicating that the nanomembrane could hold the glycerol in the reaction medium 
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463 1 |t Vol. 64, iss. 27  |v P. 13795-13810  |d 2025 
610 1 |a Alcohols 
610 1 |a Biodiesel 
610 1 |a Lipids 
610 1 |a Liquids 
610 1 |a Membranes 
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701 1 |a Piskunova  |b A. E.  |c specialist in the field of thermal power engineering and heat engineering  |c research engineer at Tomsk Polytechnic University  |f 1998-  |g Aleksandra Evgenjevna  |9 88489 
701 1 |a Khomutov  |b N. A.  |c specialist in the field of thermal power engineering and heat engineering  |c research engineer at Tomsk Polytechnic University  |f 1997-  |g Nikita Andreevich  |9 23010 
701 1 |a Ashikhmin  |b A. E.  |c Specialist in the field of thermal power engineering and heat engineering  |c Research Engineer of Tomsk Polytechnic University  |f 1998-  |g Alexander Evgenjevich  |9 23065 
701 1 |a Chobotova  |b V. M.  |c specialist in the field of thermal power engineering and heat engineering  |c Research Engineer of Tomsk Polytechnic University  |f 2002-  |g Vladlena Mikhaylovna  |9 89219 
701 1 |a Di Martino  |b A.  |c organic chemist  |c research of Tomsk Polytechnic University  |f 1984-  |g Antonio  |9 20983 
701 1 |a Melnik  |b E. Yu.  |c material science specialist  |c engineer of Tomsk Polytechnic University  |f 1998-  |g Evgeniy Yurjevich  |9 22996 
701 1 |a Bolbasov  |b E. N.  |c physicist  |c Senior Researcher at Tomsk Polytechnic University, Candidate of Technical Sciences  |f 1981-  |g Evgeny Nikolaevich  |9 15103 
701 1 |a Piskunov  |b M. V.  |c specialist in the field of thermal engineering  |c engineer of Tomsk Polytechnic University  |f 1991-  |g Maksim Vladimirovich  |9 17691 
701 1 |a Strizhak  |b P. A.  |c Specialist in the field of heat power energy  |c Doctor of Physical and Mathematical Sciences (DSc), Professor of Tomsk Polytechnic University (TPU)  |f 1985-  |g Pavel Alexandrovich  |9 15117 
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