Первые исследования сверхтонкой квадрупольной вращательной структуры винилхлорида (C2H3 35Cl) в высоковозбужденных вращательных состояниях
| Parent link: | Перспективы развития фундаментальных наук=Prospects of Fundamental Sciences Development: сборник научных трудов XХII Международной конференции студентов, аспирантов и молодых ученых, г. Томск, 22-25 апреля 2025/ Национальный исследовательский Томский политехнический университет ; под ред. И. А. Курзиной [и др.].— .— Томск: Изд-во ТПУ Т. 1 : Физика.— 2025.— С. 269-271 |
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| Streszczenie: | Заглавие с экрана In the present study, the analysis of high-resolution rotational spectra of C2H3 35Cl was performed. The absorption spectra were registered in submillimeter-wave regions from 170 up to 1100 GHz in Universität zu Köln (Germany). About 5100 line positions for the values of quantum numbers up to Jmax = 93 and Kmax a = 27 were assigned to the ground vibrational state. The fit of the parameters of the Hamiltonian and of the quadrupole splitting χ−parameters was made. The obtained set of twenty three rotational and centrifugal distortion parameters and two χ−parameters reproduces quadrupole–rotational transitions with the drms = 20 kHz Текстовый файл |
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2025
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| Dostęp online: | http://earchive.tpu.ru/handle/11683/132867 |
| Format: | Elektroniczne Rozdział |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=682465 |
| Streszczenie: | Заглавие с экрана In the present study, the analysis of high-resolution rotational spectra of C2H3 35Cl was performed. The absorption spectra were registered in submillimeter-wave regions from 170 up to 1100 GHz in Universität zu Köln (Germany). About 5100 line positions for the values of quantum numbers up to Jmax = 93 and Kmax a = 27 were assigned to the ground vibrational state. The fit of the parameters of the Hamiltonian and of the quadrupole splitting χ−parameters was made. The obtained set of twenty three rotational and centrifugal distortion parameters and two χ−parameters reproduces quadrupole–rotational transitions with the drms = 20 kHz Текстовый файл |
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