Synthesis of high-entropy diboride TiZrNbHfTaB2 by vacuum-free direct current arc plasma method; International Journal of Refractory Metals and Hard Materials; Vol. 134

Dades bibliogràfiques
Parent link:International Journal of Refractory Metals and Hard Materials.— .— Amsterdam: Elsevier Science Publishing Company Inc.
Vol. 134.— 2026.— Article number 107417, 7 p.
Altres autors: Pak A. Ya. Aleksandr Yakovlevich, Povalyaev P. V. Pavel Vadimovich, Vlasov A, V. Aleksey Vladimirovich, Gerasimov R. D. Roman Dmitrievich, Bolatova Zh. S. Zhanar Sanatovna, Svinukhova A. A. Arina Andreevna, Spodina A. V. Anastasiya Vyacheslavovna, Vasiljeva (Vassilyeva) Yu. Z. Yuliya Zakharovna
Sumari:Title screen
The study is the first to demonstrate the potential for synthesizing micro- and nanosized particles of high-entropy boride (HEB) TiZrNbHfTaB2 by vacuum-free electric arc method. Arcing induces the formation of carbon monoxide and carbon dioxide, providing a self-shielding effect of the reaction volume from atmospheric oxygen, which shifts the reaction towards boride formation. The synthesis product was identified as a solid solution with the AlB2-type hexagonal lattice, containing atoms of titanium, zirconium, niobium, hafnium, and tantalum. The lattice parameters of the HEB TiZrNbHfTaB2 phase were a = 3.1045 Å and c = 3.3775 Å. The analysis of the synthesis product revealed agglomerates of micron-sized particles consisting of individual particles, as well as nanosized particles. Bulk ceramic samples were fabricated by spark plasma sintering. The optimal sintering parameters were as follows: 2000 °C, 10 MPa, 5 min at a heating rate of 100 °C/min. Studies were conducted to determine the mechanical and thermophysical properties of the bulk HEB sample
Текстовый файл
AM_Agreement
Idioma:anglès
Publicat: 2026
Matèries:
Accés en línia:https://doi.org/10.1016/j.ijrmhm.2025.107417
Format: Electrònic Capítol de llibre
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=682394

MARC

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330 |a The study is the first to demonstrate the potential for synthesizing micro- and nanosized particles of high-entropy boride (HEB) TiZrNbHfTaB2 by vacuum-free electric arc method. Arcing induces the formation of carbon monoxide and carbon dioxide, providing a self-shielding effect of the reaction volume from atmospheric oxygen, which shifts the reaction towards boride formation. The synthesis product was identified as a solid solution with the AlB2-type hexagonal lattice, containing atoms of titanium, zirconium, niobium, hafnium, and tantalum. The lattice parameters of the HEB TiZrNbHfTaB2 phase were a = 3.1045 Å and c = 3.3775 Å. The analysis of the synthesis product revealed agglomerates of micron-sized particles consisting of individual particles, as well as nanosized particles. Bulk ceramic samples were fabricated by spark plasma sintering. The optimal sintering parameters were as follows: 2000 °C, 10 MPa, 5 min at a heating rate of 100 °C/min. Studies were conducted to determine the mechanical and thermophysical properties of the bulk HEB sample 
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610 1 |a High-entropy diboride 
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701 1 |a Pak  |b A. Ya.  |c specialist in the field of electrical engineering  |c Professor of Tomsk Polytechnic University, Doctor of Technical Sciences  |f 1986-  |g Aleksandr Yakovlevich  |9 17660 
701 1 |a Povalyaev  |b P. V.   |c specialist in the field of automatic control  |c senior laboratory assistant, junior researcher at Tomsk Polytechnic University  |f 1997-  |g Pavel Vadimovich  |9 22921 
701 1 |a Vlasov  |b A, V.  |c specialist in the field of informatics and computer technology  |c Laboratory assistant, Associate Scientist of Tomsk Polytechnic University  |f 1997-  |g Aleksey Vladimirovich  |9 88654 
701 1 |a Gerasimov  |b R. D.  |c specialist in the field of automatic control  |c Associate Scientist of Tomsk Polytechnic University  |f 1997-  |g Roman Dmitrievich  |9 23042 
701 1 |a Bolatova  |b Zh. S.  |c specialist in the field of material science  |c engineer, junior researcher at Tomsk Polytechnic University  |f 1996-  |g Zhanar Sanatovna  |9 22679 
701 1 |a Svinukhova  |b A. A.  |c specialist in the field of electric power engineering  |c Engineer of Tomsk Polytechnic University  |f 1999-  |g Arina Andreevna  |9 88548 
701 1 |a Spodina  |b A. V.  |g Anastasiya Vyacheslavovna  |f 2006-  |c Senior laboratory assistant, technician of Tomsk Polytechnic University  |y Tomsk  |7 ba  |8 eng  |9 88987 
701 1 |a Vasiljeva (Vassilyeva)  |b Yu. Z.  |c specialist in the field of electric power engineering  |c Researcher, Associate Professor of Tomsk Polytechnic University, Candidate of Technical Sciences  |f 1995-  |g Yuliya Zakharovna  |9 22376 
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