Doubly excited (v4=2) vibrational state of 12CH2 35 Cl2: Centrifugal distortion and quadrupole splittings in the submillimeter wave spectra up to 1.1 THz; Journal of Quantitative Spectroscopy and Radiative Transfer; Vol. 346
| Parent link: | Journal of Quantitative Spectroscopy and Radiative Transfer.— .— Amsterdam: Elsevier Science Publishing Company Inc. Vol. 346.— 2025.— Article number 109585, 6 p. |
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| Další autoři: | , , , , |
| Shrnutí: | Title screen The high resolution submillimeter wave spectra of the CH Cl methylene chloride (six spectra were recorded in different parts of the 0.075–1.1 THz spectral region in the I. Physikalisches Institut, Universität zu Köln (Germany) and Laboratoire PhLAM, Université de Lille (France)) were analyzed in the frame of Watson’s Hamiltonian in reduction and representation with the use of the SPFIT/SPCAT package of Pickett. The 2368 unresolved lines (including 878 peripheral lines of triplets) with the maximum values of quantum number and were assigned in the experimental spectra to the vibrational state. Weighted fit of the rotational and centrifugal distortion parameters, as well as, of the nuclear quadrupole splitting parameters was made. The eleven rotational and centrifugal distortion parameters and three nuclear quadrupole coupling parameters obtained from the fit reproduce values of the experimental multiplet centers with the root mean square deviation of 36 kHz and of the experimental peripheral lines of triplets with kHz. Comparison with the rotational and centrifugal distortion parameters of the vibrational state known in the literature is made and shown that they reproduce the same set of the experimental line positions with that is 130 times worse in comparison with the results of the present study. As to the quadrupole coupling parameters, it was found that the three parameters obtained in the fit correlate very well with the corresponding parameters from the recent paper by Z. Kisiel (J Mol Spectrosc 2024;406:111954) Текстовый файл AM_Agreement |
| Jazyk: | angličtina |
| Vydáno: |
2025
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| Témata: | |
| On-line přístup: | https://doi.org/10.1016/j.jqsrt.2025.109585 |
| Médium: | MixedMaterials Elektronický zdroj Kapitola |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=681819 |
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| 200 | 1 | |a Doubly excited (v4=2) vibrational state of 12CH2 35 Cl2: Centrifugal distortion and quadrupole splittings in the submillimeter wave spectra up to 1.1 THz |f O. N. Ulenikov, O. V. Gromova, E. S. Bekhtereva [et al.] | |
| 203 | |a Текст |b визуальный |c электронный | ||
| 283 | |a online_resource |2 RDAcarrier | ||
| 300 | |a Title screen | ||
| 320 | |a References: 35 tit | ||
| 330 | |a The high resolution submillimeter wave spectra of the CH Cl methylene chloride (six spectra were recorded in different parts of the 0.075–1.1 THz spectral region in the I. Physikalisches Institut, Universität zu Köln (Germany) and Laboratoire PhLAM, Université de Lille (France)) were analyzed in the frame of Watson’s Hamiltonian in reduction and representation with the use of the SPFIT/SPCAT package of Pickett. The 2368 unresolved lines (including 878 peripheral lines of triplets) with the maximum values of quantum number and were assigned in the experimental spectra to the vibrational state. Weighted fit of the rotational and centrifugal distortion parameters, as well as, of the nuclear quadrupole splitting parameters was made. The eleven rotational and centrifugal distortion parameters and three nuclear quadrupole coupling parameters obtained from the fit reproduce values of the experimental multiplet centers with the root mean square deviation of 36 kHz and of the experimental peripheral lines of triplets with kHz. Comparison with the rotational and centrifugal distortion parameters of the vibrational state known in the literature is made and shown that they reproduce the same set of the experimental line positions with that is 130 times worse in comparison with the results of the present study. As to the quadrupole coupling parameters, it was found that the three parameters obtained in the fit correlate very well with the corresponding parameters from the recent paper by Z. Kisiel (J Mol Spectrosc 2024;406:111954) | ||
| 336 | |a Текстовый файл | ||
| 371 | 0 | |a AM_Agreement | |
| 461 | 1 | |t Journal of Quantitative Spectroscopy and Radiative Transfer |c Amsterdam |n Elsevier Science Publishing Company Inc. | |
| 463 | 1 | |t Vol. 346 |v Article number 109585, 6 p. |d 2025 | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a Quadrupole splitting in methylene chloride | |
| 610 | 1 | |a Isotopologues of methylene chloride | |
| 610 | 1 | |a Rotational and centrifugal distortion parameters | |
| 701 | 1 | |a Ulenekov (Ulenikov) |b O. N. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1949- |g Oleg Nikolaevich |9 17837 | |
| 701 | 1 | |a Gromova |b O. V. |c physicist |c Professor of Tomsk Polytechnic University, Candidate of physical and mathematical sciences |f 1982- |g Olga Vasilievna |9 17839 | |
| 701 | 1 | |a Bekhtereva |b E. S. |c physicist |c Professor of Tomsk Polytechnic University, Doctor of physical and mathematical sciences |f 1974- |g Elena Sergeevna |9 17851 | |
| 701 | 1 | |a Nikolaeva |b V. E. |g Valeriya Evgenjevna | |
| 701 | 1 | |a Gorbacheva |b E,. D. |g Ekaterina Dmitrievna | |
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