Kinetics of Thermal Decomposition of Polymethylmethacrylate in a Carbon Dioxide Environment; Russian Journal of Physical Chemistry B; Vol. 18, iss. 4

Kinetics of Thermal Decomposition of Polymethylmethacrylate in a Carbon Dioxide Environment; Russian Journal of Physical Chemistry B; Vol. 18, iss. 4

Dettagli Bibliografici
Parent link:	Russian Journal of Physical Chemistry B.— .— New York: Springer Science+Business Media LLC Vol. 18, iss. 4.— 2024.— P. 918–923
Autore principale:	Salgansky E. A. Evgeny Aleksandrovich
Altri autori:	Salganskaya M. V., Glushkov D. O. Dmitry Olegovich
Riassunto:	Title screen A thermogravimetric analysis of the thermal decomposition of polymethylmethacrylate (PMMA) in a carbon dioxide flow is carried out. The kinetic constants of the process are determined. The heating rate of the sample varies over in wide range and amounts to 2, 5, 8, 20, 35, and 50 K/min. The values of the kinetic constants of PMMA decomposition are determined using the isoconversional method. For the degree of conversion of the substance ranging from 10 to 90%, the values of activation energy for the thermal decomposition of PMMA vary in the range from 213.5 to 194.3 kJ/mol, and the values of the preexponential coefficient change in the range from 1.62 × 1016 to 6.85 × 1012 1/s. The average activation energy for the thermal decomposition of PMMA in a carbon dioxide flow is 206 kJ/mol Текстовый файл AM_Agreement
Lingua:	inglese
Pubblicazione:	2024
Soggetti:	электронный ресурс труды учёных ТПУ PMMA TGA thermal decomposition kinetics carbon dioxide
Accesso online:	https://doi.org/10.1134/S1990793124700520 https://elibrary.ru/item.asp?id=69169048
Natura:	Elettronico Capitolo di libro
KOHA link:	https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=681764

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