Application of X-ray diffractometry and simultaneous thermal analysis for studying the phase composition of barium ferrites; Russian Journal of Nondestructive Testing; Vol. 68, iss. 3

Application of X-ray diffractometry and simultaneous thermal analysis for studying the phase composition of barium ferrites; Russian Journal of Nondestructive Testing; Vol. 68, iss. 3

Detalles Bibliográficos
Parent link:Russian Journal of Nondestructive Testing=Дефектоскопия.— .— New York: Springer Science+Business Media LLC.
Vol. 68, iss. 3.— 2025.— P. 452–460
Outros autores: Bobuyok S. A. Sergey Andreevich, Surzhikov A. P. Anatoly Petrovich, Nikolaev E. V. Evgeny Vladimirovich, Vlasov V. A. Vitaliy Anatolievich, Lysenko E. N. Elena Nikolaevna
Summary:Unsubstituted and complex substituted barium ferrites of a magnetoplumbite structure of the following compositions: BaFe12O19, BaFe11.8Al0.2O19, BaZn0.2Zr0.2Fe11.6O19 and BaZn0.2Zr0.2Al0.2Fe11.4O19 are studied. The main focus is on their phase compositions and magnetic phase transitions within the Curie temperature interval. The common patterns of variation in the ferrite crystal lattice volume as a function of the substituting cation sizes are revealed. During a simultaneous thermal analysis in the magnetic field, a correlation is observed between the instrumental variation of the sample weight and the changes of their heat capacity in the Curie temperature region. It is found out that the temperature range of the magnetic phase transition increases with the increasing content of the elements substituting iron atoms, while the Curie temperature decreases. It is shown that a thermal analysis allows effectively separating the phases in the mixture of composite powders of BaFe12O19—BaZn0.2Zr0.2Al0.2Fe11.4O19, not possible using X ray diffraction due to very small differences in the crystal lattice parameters of these two ferrite phases, causing an overlapping of their peaks in the XRD pattern. The results of this study emphasize the importance of using the simultaneous thermal analysis during the examination of phase compositions of multicomponent magnetic materials
Текстовый файл
AM_Agreement
Idioma:inglés
Publicado: 2025
Subjects:
Barium ferrite
X‑ray diffraction analysis
Thermogravimetry
Differential scanning calorimetry
Curie temperature
электронный ресурс
труды учёных ТПУ
Acceso en liña:https://doi.org/10.1007/s11182-025-03452-w
Formato: Electrónico Capítulo de libro
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=681693

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