Ce(IV)-MOF supported bimetallic NiPt nanoparticles for efficient hydrogen generation from ammonia borane hydrolysis; Chemical Synthesis; Vol. 5, iss. 51

Opis bibliograficzny
Parent link:Chemical Synthesis.— .— Alhambra: OAE Publishing Inc.
Vol. 5, iss. 51.— 2025.— 13 p.
Kolejni autorzy: Xinshun Chen, Siyu Hao, Jiapei Wang, Lixin Xu, Shenglai Li, Chao Wan, Postnikov P. S. Pavel Sergeevich
Streszczenie:Title screen
Supported bimetallic catalysts exhibit excellent catalytic activity in the hydrogen generation reaction for hydrogen storage materials, where the synergism interaction between the support and the metal needs to be explored. In this work, highly crystalline cerium-based metal-organic framework (CeMOF) supports were prepared to support NiPt alloy nanoparticles for the ammonia borane (AB) hydrolysis. CeMOF supports not only possess stable structural properties and low synthesis costs, but also provide more active sites to facilitate AB hydrolysis. The optimal catalyst, Ni0.6Pt0.4/CeMOF, exhibits a significant turnover frequency (11.07 molH2·molPt·min-1) at 298 K, with the conversion of AB reaching 100%. This work contributes a new, cost-effective approach for designing efficient catalysts that can be used in hydrogen generation systems, which is important for the development of sustainable energy storage technologies
Текстовый файл
Język:angielski
Wydane: 2025
Hasła przedmiotowe:
Dostęp online:https://doi.org/10.20517/cs.2024.156
Format: Elektroniczne Rozdział
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=681339

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330 |a Supported bimetallic catalysts exhibit excellent catalytic activity in the hydrogen generation reaction for hydrogen storage materials, where the synergism interaction between the support and the metal needs to be explored. In this work, highly crystalline cerium-based metal-organic framework (CeMOF) supports were prepared to support NiPt alloy nanoparticles for the ammonia borane (AB) hydrolysis. CeMOF supports not only possess stable structural properties and low synthesis costs, but also provide more active sites to facilitate AB hydrolysis. The optimal catalyst, Ni0.6Pt0.4/CeMOF, exhibits a significant turnover frequency (11.07 molH2·molPt·min-1) at 298 K, with the conversion of AB reaching 100%. This work contributes a new, cost-effective approach for designing efficient catalysts that can be used in hydrogen generation systems, which is important for the development of sustainable energy storage technologies 
336 |a Текстовый файл 
461 1 |t Chemical Synthesis  |c Alhambra  |n OAE Publishing Inc. 
463 1 |t Vol. 5, iss. 51  |v 13 p.  |d 2025 
610 1 |a ammonia borane 
610 1 |a hydrogen production 
610 1 |a CeMOF 
610 1 |a NiPt alloy nanoparticles 
610 1 |a электронный ресурс 
610 1 |a труды учёных ТПУ 
701 0 |a Xinshun Chen 
701 0 |a Siyu Hao 
701 0 |a Jiapei Wang 
701 0 |a Lixin Xu 
701 0 |a Shenglai Li 
701 0 |a Chao Wan 
701 1 |a Postnikov  |b P. S.  |c organic chemist  |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences  |f 1984-  |g Pavel Sergeevich  |9 15465 
801 0 |a RU  |b 63413507  |c 20250822  |g RCR 
856 4 |u https://doi.org/10.20517/cs.2024.156  |z https://doi.org/10.20517/cs.2024.156 
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