Exploring the Impact of Bi Content in Nanostructured Pd-Bi Catalysts Used for Selective Oxidation of Glucose: Synthesis, Characterization and Catalytic Properties; Inorganics; Vol. 13, iss. 6
| Parent link: | Inorganics.— .— Basel: MDPI AG Vol. 13, iss. 6.— 2025.— Article number 205, 19 p. |
|---|---|
| Andre forfattere: | Shcherbakova-Sandu M. P. Mariya, Gulevich S. A. Semyon, Meshcheryakov E. P. Eugene, Kazantseva K. I. Kseniya, Chernyavskii A. V. Aleksandr, Pestryakov A. N. Aleksey Nikolaevich, Kushwaha A. Ajay, Ritunesh K. Kumar, Sonwane A. Akshay, Samal S. Sonali, Kurzina I. A. Irina Aleksandrovna |
| Summary: | Title screen This work is devoted to the study of the effect of small Bi additives on the functional properties of Pdx:Bi/Al2O3 catalysts in the selective oxidation of glucose to gluconic acid. The catalysts obtained by the joint impregnation method were characterized (TEM) by high dispersion of bimetallic nanoparticles with a median diameter of 4–5 nm. The structure of the Pd-Bi solid solution was confirmed via XPS and showed a change in the valence state of Pd and Bi depending on the Bi content, as well as the fraction of the oxidized state of Bi. TPR-H2 revealed various forms of Pd, including PdO and mixed Pd-O-Bi structures. The Pd10:Bi1/Al2O3 catalyst demonstrated the highest efficiency (77.2% glucose conversion, 96% sodium gluconate selectivity), which is due to the optimal ratio between Pd and Bi, ensuring the stabilization of metallic Pd and preventing its oxidation Текстовый файл |
| Sprog: | engelsk |
| Udgivet: |
2025
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| Fag: | |
| Online adgang: | https://doi.org/10.3390/inorganics13060205 |
| Format: | Electronisk Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=681301 |
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