Redetermination of the crystal structure of caesium tetrafluoridobromate(III) from single-crystal X-ray diffraction data; IUCrData; Vol. 5, Pt. 1
| Parent link: | IUCrData.— .— Chester: IUCr Vol. 5, Pt. 1.— 2020.— Article number x200114. 3 p. |
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| Other Authors: | , , , |
| Summary: | Title screen Caesium tetra¬fluorido¬bromate(III), CsBrF4, was crystallized in form of small blocks by melting and recrystallization. The crystal structure of CsBrF4 was redetermined from single-crystal X-ray diffraction data. In comparison with a previous study based on powder X-ray diffraction data [Ivlev et al. (2013 ). Z. Anorg. Allg. Chem. 639, 2846–2850], bond lengths and angles were determined with higher precision, and all atoms were refined with anisotropic displacement parameters. It was confirmed that the structure of CsBrF4 contains two square-planar [BrF4]− anions each with point group symmetry mmm, and a caesium cation (site symmetry mm2) that is coordinated by twelve fluorine atoms, forming an anti¬cubocta¬hedron. CsBrF4 is isotypic with CsAuF4 Текстовый файл |
| Language: | English |
| Published: |
2020
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| Subjects: | |
| Online Access: | https://iucrdata.iucr.org/x/issues/2020/01/00/wm4121/index.html |
| Format: | Electronic Book Chapter |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=681024 |
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| 200 | 1 | |a Redetermination of the crystal structure of caesium tetrafluoridobromate(III) from single-crystal X-ray diffraction data |f Artem V. Malin, Sergei I. Ivlev, Roman V. Ostvald, Florian Kraus | |
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| 330 | |a Caesium tetra¬fluorido¬bromate(III), CsBrF4, was crystallized in form of small blocks by melting and recrystallization. The crystal structure of CsBrF4 was redetermined from single-crystal X-ray diffraction data. In comparison with a previous study based on powder X-ray diffraction data [Ivlev et al. (2013 ). Z. Anorg. Allg. Chem. 639, 2846–2850], bond lengths and angles were determined with higher precision, and all atoms were refined with anisotropic displacement parameters. It was confirmed that the structure of CsBrF4 contains two square-planar [BrF4]− anions each with point group symmetry mmm, and a caesium cation (site symmetry mm2) that is coordinated by twelve fluorine atoms, forming an anti¬cubocta¬hedron. CsBrF4 is isotypic with CsAuF4 | ||
| 336 | |a Текстовый файл | ||
| 461 | 1 | |t IUCrData |c Chester |n IUCr | |
| 463 | 1 | |t Vol. 5, Pt. 1 |v Article number x200114. 3 p. |d 2020 | |
| 610 | 1 | |a crystal structure | |
| 610 | 1 | |a caesium | |
| 610 | 1 | |a tetrafluoridobromate(III) | |
| 610 | 1 | |a redetermination | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 701 | 1 | |a Malin |b A. V. |c chemical engineer |c engineer of Tomsk Polytechnic University |f 1992- |g Artem Vladimirovich |9 21553 | |
| 701 | 1 | |a Ivlev |b S. I. |c Chemical Engineer |c assistant Tomsk Polytechnic University, candidate of chemical Sciences |f 1987- |g Sergey Ivanovich |9 15454 | |
| 701 | 1 | |a Ostvald |b R. V. |c Chemical Engineer |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences |f 1980- |g Roman Vyacheslavovich |9 15416 | |
| 701 | 1 | |a Kraus |b F. |g Florian | |
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