N-Heterocycle-coordinated λ5-iodanes as IBX alternatives for alcohol oxidations; Chemical Communications; Vol. 61

N-Heterocycle-coordinated λ5-iodanes as IBX alternatives for alcohol oxidations; Chemical Communications; Vol. 61

Bibliographic Details
Parent link:Chemical Communications.— .— Cambridge: RSC Publishing
Vol. 61.— 2025.— P. 756-759
Other Authors: Antonkin N. S. Nikita Sergeevich, Vlasenko Yu. A. Yuliya Aleksandrovna, Puylaert P. Pim, Nachtsheim B. J. Boris, Postnikov P. S. Pavel Sergeevich
Summary:Title screen
We report the synthesis of novel N-coordinated λ5-iodanes as a unique class of hypervalent iodine compounds. X-ray diffraction analysis revealed their intriguing (pseudo)cyclic structure, showcasing distinctive N⋯I-secondary bonding interactions. We demonstrate the in situ generation of reactive diacetoxy derivatives, which exhibits remarkable efficacy in alcohol oxidation reactions. Thermal stability assessments using TGA/DSC analysis provide crucial insights into the handling and potential applications of these compounds. This work expands the frontier of hypervalent iodine chemistry, offering new tools for selective oxidation reactions
Текстовый файл
AM_Agreement
Language:English
Published: 2025
Subjects:
электронный ресурс
труды учёных ТПУ
synthesis
X-ray diffraction analysis
alcohol oxidation reactions
Online Access:https://doi.org/10.1039/D4CC05058D
Format: Electronic Book Chapter
KOHA link:https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=680718

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