N-Heterocycle-coordinated λ5-iodanes as IBX alternatives for alcohol oxidations; Chemical Communications; Vol. 61
| Parent link: | Chemical Communications.— .— Cambridge: RSC Publishing Vol. 61.— 2025.— P. 756-759 |
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| Muut tekijät: | , , , , |
| Yhteenveto: | Title screen We report the synthesis of novel N-coordinated λ5-iodanes as a unique class of hypervalent iodine compounds. X-ray diffraction analysis revealed their intriguing (pseudo)cyclic structure, showcasing distinctive N⋯I-secondary bonding interactions. We demonstrate the in situ generation of reactive diacetoxy derivatives, which exhibits remarkable efficacy in alcohol oxidation reactions. Thermal stability assessments using TGA/DSC analysis provide crucial insights into the handling and potential applications of these compounds. This work expands the frontier of hypervalent iodine chemistry, offering new tools for selective oxidation reactions Текстовый файл AM_Agreement |
| Kieli: | englanti |
| Julkaistu: |
2025
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| Aiheet: | |
| Linkit: | https://doi.org/10.1039/D4CC05058D |
| Aineistotyyppi: | Elektroninen Kirjan osa |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=680718 |
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| 200 | 1 | |a N-Heterocycle-coordinated λ5-iodanes as IBX alternatives for alcohol oxidations |f Nikita S. Antonkin, Yulia A. Vlasenko, Pim Puylaert [et al.] | |
| 283 | |a online_resource |2 RDAcarrier | ||
| 300 | |a Title screen | ||
| 320 | |a References: 47 tit | ||
| 330 | |a We report the synthesis of novel N-coordinated λ5-iodanes as a unique class of hypervalent iodine compounds. X-ray diffraction analysis revealed their intriguing (pseudo)cyclic structure, showcasing distinctive N⋯I-secondary bonding interactions. We demonstrate the in situ generation of reactive diacetoxy derivatives, which exhibits remarkable efficacy in alcohol oxidation reactions. Thermal stability assessments using TGA/DSC analysis provide crucial insights into the handling and potential applications of these compounds. This work expands the frontier of hypervalent iodine chemistry, offering new tools for selective oxidation reactions | ||
| 336 | |a Текстовый файл | ||
| 371 | 0 | |a AM_Agreement | |
| 461 | 1 | |t Chemical Communications |c Cambridge |n RSC Publishing | |
| 463 | 1 | |t Vol. 61 |v P. 756-759 |d 2025 | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a synthesis | |
| 610 | 1 | |a X-ray diffraction analysis | |
| 610 | 1 | |a alcohol oxidation reactions | |
| 701 | 1 | |a Antonkin |b N. S. |c chemist |c engineer of Tomsk Polytechnic University |f 1996- |g Nikita Sergeevich |9 22242 | |
| 701 | 1 | |a Vlasenko |b Yu. A. |c chemist |c engineer of Tomsk Polytechnic University |f 1994- |g Yuliya Aleksandrovna |9 21652 | |
| 701 | 1 | |a Puylaert |b P. |g Pim | |
| 701 | 1 | |a Nachtsheim |b B. J. |g Boris | |
| 701 | 1 | |a Postnikov |b P. S. |c organic chemist |c Associate Professor of Tomsk Polytechnic University, Candidate of chemical sciences |f 1984- |g Pavel Sergeevich |9 15465 | |
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