The influence of single-walled carbon nanotubes additives on the structure and hydrogenation behavior of magnesium hydride
| Parent link: | Journal of Energy Storage.— .— Amsterdam: Elsevier Science Publishing Company Inc. Vol. 119.— 2025.— Article number 116408, 16 p. |
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| Muut tekijät: | , , , |
| Yhteenveto: | Title screen One of the most preferred candidates for hydrogen storage and purification are metal hydrides and composites based on them. In this paper, one of the high-capacity composite materials for hydrogen storage based on Mg/MgH2 and single-walled carbon nanotubes is considered. It was confirmed that the hydrogen storage efficiency of Mg/MgH2 can be improved by doping with carbon nanotubes with Fe nanoparticles remaining in the nanotubes after their growth. Using TEM microscopy, it was shown that carbon nanotubes are uniformly distributed over the surface of Mg/MgH2 particles, and some of the nanotubes are partially embedded in the bulk of Mg/MgH2. Iron nanoparticles are deposited from the nanotubes on the surface of magnesium particles as well. These carbon nanotubes and iron nanoparticles cause defects and serve as nucleation sites for new phases that are formed in the process of hydrogenation and dehydrogenation reactions. It was found that the activation energies of Mg/MgH2 hydrogen absorption and dehydrogenation decreased by 13 and 24 kJ/mol, respectively, using experimental hydrogen sorption-desorption data and the Kolmogorov–Johnson–Mehl–Avrami equation. In addition, the Mg/MgH2 + 5wt%SWCNT composite absorb 4.8 wt% H2 in 6000 s, while Mg/MgH2 can absorb 4.3 wt% H2 in 6000 s at a temperature of 563 K and a pressure of 3 MPa. However, Mg/MgH2 can release about 5.2 wt% H2 within 6000 s, while Mg/MgH2 + 5wt%SWCNT composite showed 4.8 wt% H2 desorbed in the same time. Cycling stability testing showed that the hydrogen storage capacity of the Mg/MgH2 + 5wt%SWCNT remained almost unchanged during 10 cycles due to the reduction in particle agglomeration by the addition of carbon nanotubes, which was confirmed by SEM images of composite. Mg/MgH2 + 5wt%SWCNT composite was characterized by in situ defect structure analysis during hydrogen sorption process using positron annihilation spectroscopy method. According to the results obtained, a scheme of the hydrogen sorption by magnesium and the Mg/MgH2 + 5wt%SWCNT composite was suggested Текстовый файл AM_Agreement |
| Kieli: | englanti |
| Julkaistu: |
2025
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| Aiheet: | |
| Linkit: | https://doi.org/10.1016/j.est.2025.116408 |
| Aineistotyyppi: | Elektroninen Kirjan osa |
| KOHA link: | https://koha.lib.tpu.ru/cgi-bin/koha/opac-detail.pl?biblionumber=679564 |
MARC
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| 200 | 1 | |a The influence of single-walled carbon nanotubes additives on the structure and hydrogenation behavior of magnesium hydride |f Roman R. Elman, Nikita Kurdyumov, Roman S. Laptev, Viktor N. Kudiiarov | |
| 203 | |a Текст |b визуальный |c электронный | ||
| 283 | |a online_resource |2 RDAcarrier | ||
| 300 | |a Title screen | ||
| 320 | |a References: 106 tit | ||
| 330 | |a One of the most preferred candidates for hydrogen storage and purification are metal hydrides and composites based on them. In this paper, one of the high-capacity composite materials for hydrogen storage based on Mg/MgH2 and single-walled carbon nanotubes is considered. It was confirmed that the hydrogen storage efficiency of Mg/MgH2 can be improved by doping with carbon nanotubes with Fe nanoparticles remaining in the nanotubes after their growth. Using TEM microscopy, it was shown that carbon nanotubes are uniformly distributed over the surface of Mg/MgH2 particles, and some of the nanotubes are partially embedded in the bulk of Mg/MgH2. Iron nanoparticles are deposited from the nanotubes on the surface of magnesium particles as well. These carbon nanotubes and iron nanoparticles cause defects and serve as nucleation sites for new phases that are formed in the process of hydrogenation and dehydrogenation reactions. It was found that the activation energies of Mg/MgH2 hydrogen absorption and dehydrogenation decreased by 13 and 24 kJ/mol, respectively, using experimental hydrogen sorption-desorption data and the Kolmogorov–Johnson–Mehl–Avrami equation. In addition, the Mg/MgH2 + 5wt%SWCNT composite absorb 4.8 wt% H2 in 6000 s, while Mg/MgH2 can absorb 4.3 wt% H2 in 6000 s at a temperature of 563 K and a pressure of 3 MPa. However, Mg/MgH2 can release about 5.2 wt% H2 within 6000 s, while Mg/MgH2 + 5wt%SWCNT composite showed 4.8 wt% H2 desorbed in the same time. Cycling stability testing showed that the hydrogen storage capacity of the Mg/MgH2 + 5wt%SWCNT remained almost unchanged during 10 cycles due to the reduction in particle agglomeration by the addition of carbon nanotubes, which was confirmed by SEM images of composite. Mg/MgH2 + 5wt%SWCNT composite was characterized by in situ defect structure analysis during hydrogen sorption process using positron annihilation spectroscopy method. According to the results obtained, a scheme of the hydrogen sorption by magnesium and the Mg/MgH2 + 5wt%SWCNT composite was suggested | ||
| 336 | |a Текстовый файл | ||
| 371 | 0 | |a AM_Agreement | |
| 461 | 1 | |t Journal of Energy Storage |c Amsterdam |n Elsevier Science Publishing Company Inc. | |
| 463 | 1 | |t Vol. 119 |v Article number 116408, 16 p. |d 2025 | |
| 610 | 1 | |a электронный ресурс | |
| 610 | 1 | |a труды учёных ТПУ | |
| 610 | 1 | |a Hydrogen | |
| 610 | 1 | |a Sorption-desorption processes | |
| 610 | 1 | |a Activation energy | |
| 610 | 1 | |a Kinetics | |
| 610 | 1 | |a Magnesium hydride | |
| 610 | 1 | |a Single-walled carbon nanotubes | |
| 701 | 1 | |a Elman |b R. R. |c physicist |c Engineer of Tomsk Polytechnic University |f 1997- |g Roman Romanovich |9 22716 | |
| 701 | 1 | |a Kurdyumov |b N. |c physicist |c engineer of Tomsk Polytechnic University |f 1997- |g Nikita |9 22913 | |
| 701 | 1 | |a Laptev |b R. S. |c physicist, specialist in the field of non-destructive testing |c Associate Professor of Tomsk Polytechnic University, Doctor of Technical Sciences |f 1987- |g Roman Sergeevich |y Tomsk |9 15956 | |
| 701 | 1 | |a Kudiyarov |b V. N. |c physicist |c Associate Professor of Tomsk Polytechnic University, Candidate of Technical Sciences |f 1990- |g Victor Nikolaevich |y Tomsk |9 15083 | |
| 801 | 0 | |a RU |b 63413507 |c 20250408 | |
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| 856 | 4 | |u https://doi.org/10.1016/j.est.2025.116408 |z https://doi.org/10.1016/j.est.2025.116408 | |
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